Fabricating defect-rich metal-organic frameworks mixed linker-induced crystal transformation.

Chem Commun (Camb)

State Key Laboratory of Materials-Oriented Chemical Engineering, College of Chemical Engineering, Nanjing Tech University, Nanjing 211816, China.

Published: June 2022

Defect-rich hcp UiO-66-NO was synthesized mixed linker-induced crystal transformation from fcu UiO-66-NO/NH. The defect concentration and porosity of hcp UiO-66-NO can be fine-tuned by varying the BDC-NH/BDC-NO ratio, which in turn endowed hcp UiO-66-NO with superior catalytic performance in the ring-opening reaction of epoxides with alcohols.

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Source
http://dx.doi.org/10.1039/d2cc00923dDOI Listing

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