As the spatial dimension is lowered, locally stabilizing interactions are reduced, leading to the emergence of strongly fluctuating phases of matter without classical analogues. Here we report on the experimental observation of a one dimensional quantum liquid of He using nanoengineering by confining it within a porous material preplated with a noble gas to enhance dimensional reduction. The resulting excitations of the confined He are qualitatively different than bulk superfluid helium, and can be analyzed in terms of a mobile impurity allowing for the characterization of the emergent quantum liquid beyond the Luttinger liquid paradigm. The low dimensional helium system offers the possibility of tuning via pressure-from weakly interacting, all the way to the super Tonks-Girardeau gas of strongly interacting hard-core particles.
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http://dx.doi.org/10.1038/s41467-022-30752-3 | DOI Listing |
J Chem Phys
January 2025
Department of Chemistry, New York University, New York, New York 10003, USA.
The water trimer, as the smallest water cluster in which the three-body interactions can manifest, is arguably the most important hydrogen-bonded trimer. Accurate, fully coupled quantum treatment of its excited intermolecular vibrations has long been an elusive goal. Here, we present the methodology that for the first time allows rigorous twelve-dimensional (12D) quantum calculation of the intermolecular vibration-tunneling eigenstates of the water trimer, with the monomers treated as rigid.
View Article and Find Full Text PDFJ Phys Chem A
January 2025
Univ Rennes, CNRS, IPR (Institut de Physique de Rennes)─UMR 6251, F-35000 Rennes, France.
Chloronium (HCl) is an important intermediate of Cl-chemistry in space. The accurate knowledge of its collisional properties allows a better interpretation of the corresponding observations in interstellar clouds and, therefore, a better estimation of its abundance in these environments. While the ro-vibrational spectroscopy of HCl is well-known, the studies of its collisional excitation are rather limited and these are available for the interaction with helium atoms only.
View Article and Find Full Text PDFPhys Rev E
November 2024
Department of Mathematics and Statistics, University of Vermont, Burlington, Vermont 05405, USA.
We develop convergence acceleration procedures that enable a gradient descent-type iteration method to efficiently simulate Hartree-Fock equations for many particles interacting both with each other and with an external potential. Our development focuses on three aspects: (i) optimization of a parameter in the preconditioning operator; (ii) adoption of a technique that eliminates the slowest-decaying mode to the case of many equations (describing many particles); and (iii) a novel extension of the above technique that allows one to eliminate multiple modes simultaneously. We illustrate performance of the numerical method for the two-dimensional model of the first layer of helium atoms above a graphene sheet.
View Article and Find Full Text PDFNat Commun
December 2024
Institute of Applied Physics and Materials Engineering, University of Macau, Macau, China.
ACS Nano
November 2024
National Institute of Optics (CNR-INO), Via Nello Carrara 1, Sesto Fiorentino 50019, Italy.
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