Due to simplicity and flexibility, electrospinning technique can produce many types of fibers at nanoscale via different operational parameters for various applications including industrial wastewater treatment, air filtration and so on. Nonetheless, the study on the electrospinning operational parameter is very limited and many researchers are still using trial-and-error method to design their targeted fiber. In this study, a series of electrospun polysulfone (PSF; 20% w/v) nanofibrous membranes that made up from different ratios of dimethylformamide (DMF) and tetrahydrofuran (THF) mixtures in order to achieve different dielectric constant (ϵ) of solvent system. The fabricated PSF nanofibers were characterized by field emission scanning electron microscopy (FESEM), tensile strength tester and contact angle measurement. The THF-DMF binary solvent system with ϵ = 16.33 to 27.97 produced a smooth surface electrospun PSF nanofibers, while THF mono solvent system (ϵ = 7.60) and DMF mono solvent system (ϵ = 36.70) produced a rough and porous surface electrospun PSF nanofibers. This finding is contradicted with the common finding in which only a binary solvent is able to fabricate a rough or grooved surface electrospun nanofibers. In addition, the dielectric constant can be another key factor, besides boiling point and solubility of binary solvent system, that induces phase separation in the polymeric solution jet and eventually fabricate non-smooth surface electrospun nanofibers. The fabricated electrospun PSF nanofibrous membranes showed high efficiency in phosphate removal.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1016/j.chemosphere.2022.135228 | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Highly efficient recovery of cobalt-ion containing waste deep eutectic electrolytes: a sustainable solvent extraction approach.
ChemSusChem
January 2025
Kunming University of Science and Technology, Faculty of Metallurgical and Energy Engineering, No. 68 Wenchang Road, 121 Street, 650093, Kunming, CHINA.
Efficient recovery of metals from secondary resources is essential to address resource shortages and environmental crises. The development of a cheap, environmentally friendly, and highly efficient recovery pathway is essential for resource retrieval. In this study, we propose a high-efficiency extraction approach utilizing bis(2,4,4-trimethylpentyl) phosphonic acid (Cyanex272) to recover cobalt from waste choline chloride/ethylene glycol (Ethaline) electrolyte containing Co(II) ions.
View Article and Find Full Text PDFAssembly of Genetically Engineered Ionizable Protein Nanocage-based Nanozymes for Intracellular Superoxide Scavenging.
Nat Commun
January 2025
Key Laboratory of Bioactive Materials for the Ministry of Education, College of Life Sciences, State Key Laboratory of Medicinal Chemical Biology, and Frontier of Science Center for Cell Response, Nankai University, Tianjin, 300071, China.
Nanozymes play a pivotal role in mitigating excessive oxidative stress, however, determining their specific enzyme-mimicking activities for intracellular free radical scavenging is challenging due to endo-lysosomal entrapment. In this study, we employ a genetic engineering strategy to generate ionizable ferritin nanocages (iFTn), enabling their escape from endo-lysosomes and entry into the cytoplasm. Specifically, ionizable repeated Histidine-Histidine-Glutamic acid (9HE) sequences are genetically incorporated into the outer surface of human heavy chain FTn, followed by the assembly of various chain-like nanostructures via a two-armed polyethylene glycol (PEG).
View Article and Find Full Text PDFPhotophysical Investigation of Dyes and Dye-PMMA Systems: Insights into Absorption, Emission, and Charge Transfer Mechanisms.
J Phys Chem A
January 2025
Laboratory of Physical Chemistry, Department of Chemistry, National and Kapodistrian University of Athens, Zografou GR-15784, Greece.
The photophysical properties of five dyes, i.e., perylene, anthracene, aminoanthracene, 1,6-diphenylhexatriene, and 7-diethylamino-4-methylcoumarin, in solvent and attached to the poly(methyl methacrylate) (PMMA) polymer, were studied via DFT and TD-DFT calculations.
View Article and Find Full Text PDFLignocellulose nanofiber-enhanced hydrogel electrolytes with lignin-Al in metal-based neutral deep eutectic solvent for flexible supercapacitors.
J Colloid Interface Sci
January 2025
Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Light Industry and Food Engineering, Nanjing Forestry University, Nanjing 210037 China. Electronic address:
The mechanical flexibility and high conductivity of hydrogel electrolytes are crucial for their application in supercapacitors. In this study, we developed hydrogel electrolyte based on lignocellulose nanofibers (LCNFs) through nanofibrillation and self-catalytic gelation in a glycerinum/choline chloride/aluminum chloride hexahydrate (Gly/ChCl/AlCl·6HO) metal-based neutral deep eutectic solvent (DES) system. The lignin-Al self-catalytic mechanism offered an eco-friendly and sustainable method for synthesizing hydrogel electrolytes, while enhancing their ionic conductivity.
View Article and Find Full Text PDFGreen quantification of amino(poly)phosphonates using ion chromatography coupled to integrated pulsed amperometric detection.
Anal Bioanal Chem
January 2025
Center for Applied Geoscience, Department of Geosciences, Eberhard Karls University Tübingen, Tübingen, Germany.
Aminopolyphosphonates (APPs) are widely used as chelating agents, and their increasing release into the environment has raised concerns due to their transformation into aminomethylphosphonic acid (AMPA) and glyphosate, compounds of controversial environmental impact. This transformation highlights the urgent need for detailed studies under controlled conditions. Despite the availability of various methods for quantifying individual aminopolyphosphonates and aminomonophosphonates, a green, low-cost approach for the simultaneous quantification of APPs and their transformation products in laboratory experiments has been lacking.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!