Unlabelled: Rational composition design of trimetallic phosphide catalysts is of significant importance for enhanced surface reaction and efficient catalytic performance. Herein, hierarchical Co Ni Fe P with precise control of stoichiometric metallic elements ( = (1-10):(1-10):1) has been synthesized, and CoNiFeP, as the most optimal composition, exhibits remarkable catalytic activity ( = 320 mV at 10 mA cm) and long-term stability (ignorable decrease after 10 h continuous test at the current density of 10 mA cm) toward oxygen evolution reaction (OER). It is found that the surface P in CoNiFeP was replaced by O under the OER process. The density function theory calculations before and after long-term stability tests suggest the clear increasing of the density of states near the Fermi level of CoNiFeP/CoNiFeO, which could enhance the OH adsorption of our electrocatalysts and the corresponding OER performance.
Electronic Supplementary Material: Supplementary material is available in the online version of this article at 10.1007/s40843-022-2061-x.
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http://dx.doi.org/10.1007/s40843-022-2061-x | DOI Listing |
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