Constructing ordered macropores in hollow Co/C polyhedral nanocages shell toward superior microwave absorbing performance.

Rational design of porous carbon architecture is essential for superior microwave absorbing performance. Herein, we report a new type of hollow porous Co/C polyhedral nanocages with ordered macropores of  ∼60 nm (HP-Co/C) as microwave absorber, which were readily manufactured by epitaxial growth of ZIF-67/SiO nanolayers on the surfaces of polyhedral ZIF-8 nanoparticle, and followed by simple calcination in Ar atmosphere and subsequent removal of SiO with HF. The ordered macropores can effectively tune the electromagnetic parameters of HP-Co/C, affording the obtained HP-Co/C composites strong attenuation capability and excellent impedance matching characteristics for electromagnetic wave (EMW) absorption. As a result, the reflection loss (RL) and effective absorption bandwidth (EAB) of HP-Co/C prepared under pyrolysis temperature of 600 °C can reach up to -66.5 dB and 8.96 GHz, respectively, at filler fraction of only 15 wt%. Together, this study offers a new design philosophy to make lightweight and broadband microwave absorbent and can be extended to other types of microwave absorbers, significantly enriching the categories of the efficient microwave absorbing materials.