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Polybutadiene Functionalization via an Efficient Avenue. | LitMetric

Polybutadiene Functionalization via an Efficient Avenue.

ACS Macro Lett

Preparative Macromolecular Chemistry, Institut für Technische Chemie und Polymerchemie, Karlsruhe Institute of Technology (KIT), Engesserstraße 18, 76128 Karlsruhe, Germany.

Published: October 2016

AI Article Synopsis

Article Abstract

We introduce a facile and quantitative postpolymerization functionalization methodology for 1,4-polybutadienes, allowing us to decorate their pendent alkene functionalities with bromine and alkoxyether motifs carrying an array of functional groups ranging from tetrazoles to pyrenes. Specifically, the approach makes use of a mild, metal-free, electrophilic cascade reaction employing -bromosuccinimide (NBS), a cyclic ether (i.e., THF), and a functional carboxylic acid. Detailed NMR, SEC, and ATR-IR studies confirm the successful modification.

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Source
http://dx.doi.org/10.1021/acsmacrolett.6b00679DOI Listing

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