Controlled Pd(0)-catalyzed Suzuki cross-coupling polymerizations of AB-type monomers with tris(1-adamantyl)phosphine (AdP) as the ligand was described. AdP-coordinated acetanilide-based palladacycle complex () was demonstrated to be an efficient initiator for controlled Suzuki cross-coupling polymerization, affording polymers with narrow s and well-controlled end groups. Our study provided an efficient ligand and an efficient initiator for controlled Suzuki cross-coupling polymerizations.
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| http://dx.doi.org/10.1021/acsmacrolett.7b00759 | DOI Listing |
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