A stable (amino)plumbylene-substituted phosphaketene 3 was synthesized by the successive reactions of PbCl with two anionic reagents (lithium amidophosphine and NaPCO). Of particular interest, the thermal evolution of 3, at 80 °C, leads to the transient formation of corresponding amino- and phosphanylidene-phosphaketenes (6 and 7), via a reductive elimination at the Pb center forming new N-P and P-P bonds. Further evolution of 6 gives a new cyclic (amino)phosphanylidene phosphorane 4, which shows a unique reactivity as a phosphinidene. This result provides a new synthetic route to phosphinidenes, extending and facilitating further their access.
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| http://dx.doi.org/10.1002/chem.202201615 | DOI Listing |
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