AI Article Synopsis

  • The study explores how varying the antisolvent temperature during the washing enhanced nucleation (WEN) process affects the properties of CHNHPbI crystalline thin films and the performance of MAPbI photovoltaic cells.
  • The characterization techniques used include atomic-force microscopy, X-ray diffractometry, and photoluminescence spectrometry, revealing a shift in the crystalline phase from (110)-(002) complex to a preferred (002) phase as temperature changes.
  • The highest power conversion efficiency of the MAPbI photovoltaic cells reaches 19.30% at an antisolvent temperature of 30 °C, attributed to improved carrier collection efficiency and reduced carrier recombination.

Article Abstract

The properties of CHNHPbI(MAPbI) crystalline thin films and the device performance of highly efficient MAPbIphotovoltaic cells are investigated by varying the temperature of the antisolvent from 20 °C to 50 °C during the washing enhanced nucleation (WEN) process. The surface, structural, optoelectronic and defect properties of the perovskite thin films are characterized through atomic-force microscopy, X-ray diffractometry and photoluminescence spectrometry. The experimental results show that changing the temperature of the antisolvent during the WEN process can manipulate the MAPbIcrystalline thin films from the (110)-(002) complex phase to a (002) preferred phase. It is noted that the highest power conversion efficient of the inverted MAPbIphotovoltaic cells is 19.30%, mainly due to the increased carrier collection efficiency and reduced carrier recombination when the temperature of the antisolvent is 30 °C.

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Source
http://dx.doi.org/10.1088/1361-6528/ac7474DOI Listing

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