AI Article Synopsis
- Imines treated with palladium(II) acetate in acetic acid resulted in dinuclear complexes that can easily react with sodium halides to form μ-halide versions.
- These μ-halide complexes can then react with nucleophiles containing nitrogen, phosphorus, or oxygen, leading to the formation of new imine palladacycles after breaking down the PdX unit.
- The synthesized compounds were thoroughly characterized and successfully used as catalysts in the Suzuki-Miyaura coupling reaction in both aqueous and semi-aqueous environments.
Article Abstract
Treatment of the imines with palladium(II) acetate in acetic acid yielded the μ-acetate dinuclear complexes , which readily reacted with sodium chloride or bromide to provide μ-halide analogues. The reaction of the latter with nitrogen, phosphorus and oxygen donor nucleophiles yielded new imine palladacycles following the cleavage of the PdX unit. The complexes were fully characterized by microanalysis, H, C and P NMR spectroscopies, as appropriate. The compounds were applied as catalysts in the Suzuki-Miyaura coupling reaction in aqueous and semi-aqueous media.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9144456 | PMC |
| http://dx.doi.org/10.3390/molecules27103146 | DOI Listing |
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