Role of Liquid-Phase Amount in Ceramization of Silicone Rubber Composites and Its Controlling.

Materials (Basel)

State Key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan 430070, China.

Published: May 2022

The reliable mechanical properties of ceramizable silicone rubber composites during pyrolysis are necessary for their application in the fire-resistant fields. The effects of liquid-phase amount on the mechanical properties of silicone rubber composites are investigated. The results show a positive correlation between the liquid-phase amount and the flexural strength of the residual products pyrolysis below 800 °C. The nano-γ-AlO in the fillers reacts with liquid BO to form aluminum borate above 800 °C, which consumes the liquid phase and strengthens the residual products to a certain extent. Increasing the BO addition and introducing nano-γ-AlO can control the liquid-phase amount in the range of 15% to 30%, which makes the composites have better residual strength and support performance. The residual strength of composites pyrolysis at 500 °C to 1000 °C is higher than 2.50 MPa, and the maximum is up to 18.7 MPa at 1000 °C.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9145199PMC
http://dx.doi.org/10.3390/ma15103675DOI Listing

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