Effect of Alkali Salts on the Hydration Process of Belite Clinker.

Materials (Basel)

Faculty of Chemistry, Institute of Materials Science, Brno University of Technology, 612 00 Brno, Czech Republic.

Published: May 2022

Belite-rich cement is a low carbon footprint binder. However, its use is accompanied by a low initial rate of hydration. This can be partially eliminated by grinding to a high specific surface or through the addition of admixtures (mineralizators or activators). The influence of alkaline activators CaSO, NaSO and NaCO (in the amount of 5 wt.% related to the clinker weight) on the hydration course, as well as the quantity of hydration products in belite-rich cements, were investigated in this paper. Belite-rich clinker was laboratory-synthetized and ground together with activators to prepare various belite-rich cements. Next, the hydration kinetics and the hydrated phase assemblage were investigated using isothermal calorimetry, X-ray powder diffraction and thermogravimetric and differential thermal analyses. The use of selected admixtures allowed us to obtain belite-rich cements with higher hydraulic activity in the initial period.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9147416PMC
http://dx.doi.org/10.3390/ma15103424DOI Listing

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