Lead halide perovskite nanocrystals in a glass matrix are a promising platform for optoelectronic applications due to their excellent optical properties combined with outstanding stability against the environment. We reveal the potential of this system for spintronics by studying the electron spin properties of CsPb(Cl,Br) nanocrystals in a fluorophosphate glass matrix. Using optical spin orientation and spin depolarization with a radio frequency field, we measure longitudinal spin relaxation time, , reaching several hundreds of microseconds at low temperatures. This time corresponds to a spin state with a small factor, which we attribute to a weakly exchange-coupled electron-hole pair with antiparallel spins.
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ACS Macro Lett
January 2025
Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455, United States.
Poly(lactide) (PLA) is a promising biodegradable polymer with potential applications in single-use packaging. However, its use is limited by brittleness, and its biodegradability is restricted to industrial compost conditions due in part to an elevated glass transition temperature (). We previously showed that addition of a poly(ethylene-oxide)--poly(butylene oxide) diblock copolymer (PEO-PBO) forms macrophase-separated rubbery domains in PLA that can impart significant toughness at only 5 wt %.
View Article and Find Full Text PDFUltrasonics
December 2024
School of Mechatronic & Automation Engineering, Shanghai University, Shanghai 200444, China; Key Laboratory of Silicate Cultural Relics Conservation (Shanghai University), Ministry of Education, China. Electronic address:
Fiber reinforced polymer composites (FRPs) are essential for various industrial fields, but wrinkles inside will greatly reduce their mechanical properties. Full-matrix capture (FMC) is a popular data structure for ultrasonic phased array imaging in composites. However, such structure may lead to data redundancy and noise interference.
View Article and Find Full Text PDFACS Omega
December 2024
Department of Materials Science and Engineering, Norwegian University of Science and Technology, NTNU, Sem Sælands vei 12, 7034 Trondheim, Norway.
In thermosetting epoxies, thermomechanical properties can be enhanced by conscious selection of curing agents. Full cross-linking leads to a maximum in the glass- transition temperature. However, the relation between the glass transition temperature and the epoxy matrix depends on several factors beyond the cross-linking degree, such as the molecular weight of the polymers, network organization, amount of branching, and the presence of hydrogen bonds.
View Article and Find Full Text PDF3D Print Addit Manuf
October 2024
State Key Laboratory of Tribology, Department of Mechanical Engineering, Beijing Key Laboratory of Precision/Ultra-Precision Manufacturing Equipment Control, Tsinghua University, Beijing, China.
The use of deformable materials in 3D printing has allowed for the fabrication of intricate soft robotics prototypes. Polyjet technology, with its ability to print multiple materials in a single print, has been popular in creating such designs. Vero and Agilus, the commercial materials provided by Polyjet, possess shape memory properties, making Polyjet ideal for high-precision and transformable applications.
View Article and Find Full Text PDFCell Biochem Biophys
December 2024
School of Pharmacy, Aichi Gakuin University, 1-100 Kusumoto-cho, Chikusa-ku, Nagoya, 464-8650, Japan.
Cell-extracellular matrix (ECM) interactions play multiple roles in developmental, physiological, and pathological processes. ECM stiffness substantially affects cellular morphology, migration, and function. In this study, we investigated the effect of ECM comprising gelatin methacryloyl (GelMA) on the activation of rat basophilic leukemia (RBL-2H3) cells, a model mast cell line.
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