Modifications in curved π-electronic systems, dipyrrolylbenzodiazepines, resulted in various derivatives with modulated electronic properties and assembly behaviour. The electron-rich pyrrole-based curved π-system exhibited C complexation in the form of a hydrogen-bonding cyclic hexamer, giving rise to solid-state photo-induced electron transfer as elucidated by transient absorption spectroscopy.
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| http://dx.doi.org/10.1039/d2cp01575g | DOI Listing |
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