When reporting results of Gunshot Residue (GSR) analysis from a person suspected to be involved in a recent shooting, most forensic experts only provide the court with the raw results (i.e. the number of GSR particles found) and a disclaimer that a positive finding does not prove that the suspect was involved in a firearm shooting incident whilst a negative finding does not prove that he was not. Probabilistic analysis of the GSR results provides more value to the court, so the present study calculated likelihood ratio (LR) values for finding 0-8 characteristic GSR particles (containing Lead, Barium and Antimony) on a suspect's hands, based on the available GSR data from the published literature as well as studies by the authors. Defense propositions, i.e. modes for GSR acquisition other than involvement in a shooting event, were divided into three broad categories: low, medium and heavy background. For each background level and number of GSR particles found, minimal and maximal LR values were calculated. Thus, for each proposition the defense provides for the presence of GSR on the defendant's hands, the forensic expert can provide a possible set of minimal and maximal LR values, leaving the court to examine the defendant's contention and decide which of the three background modes is more plausible according to the circumstances of the specific case.
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http://dx.doi.org/10.1016/j.forsciint.2022.111339 | DOI Listing |
Anal Chem
January 2025
Chemical Sciences Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830, United States.
A novel employment of single particle-inductively coupled plasma-mass spectrometry (SP-ICP-MS) was developed, where a microextraction (ME) probe is used to sample nanoparticles from a surface and analyze them in a single analytical step. The effects of several parameters on the performance of ME-SP-ICP-MS were investigated, including the flow rate, choice of carrier solution, particle size, and the design of the microextraction probe head itself. The optimized ME-SP-ICP-MS technique was used to compare the extraction efficiency (EE, defined as the ratio of particles measured to particles deposited on the surface) of the commercial probe head to a newly designed SP polyether ether ketone (PEEK) probe head.
View Article and Find Full Text PDFAnalyst
November 2024
School of Materials Science and Engineering, Nanyang Technological University, 50 Nanyang Avenue, 639798, Singapore.
In firearm forensic investigations, detecting gunshot residue (GSR) is crucial for linking firearms to suspects and determining firing distance for forensic reconstruction. Matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-ToF-MS) is emerging as a versatile and promising technological platform for fingerprint analysis. The capability of functionalized particles as an advanced dusting powder for visualizing latent fingerprints is widely recognized.
View Article and Find Full Text PDFJ Forensic Sci
November 2024
University Department of Forensic Sciences, University of Split, Split, Croatia.
Inorganic gunshot residue (iGSR) analysis, crucial for linking suspects to firearm use, faces challenges from potential environmental contamination, notably in police vehicles. The present study aimed to explore the level of iGSR contamination in police vehicles from the Zagreb County Police Administration (Croatia), considering particle types and their position in vehicles, and to identify associated risk factors. From December 2021 to April 2022, 65 of 86 police vehicles (margin of error: ±6% at a 95% confidence level) were sampled with GSR stubs on the drivers' seats, back seats, and backrests and analyzed using scanning electron microscopy and energy dispersive x-ray analysis (SEM/EDX).
View Article and Find Full Text PDFSci Justice
September 2024
Ecole des Sciences Criminelles, Université de Lausanne, Switzerland. Electronic address:
During the investigation of firearm-related incidents, gunshot residues (GSR) can be collected on the scene and individuals (e.g., shooters or bystanders).
View Article and Find Full Text PDFToxicology
September 2024
Shanghai Key laboratory of Atmospheric Particle Pollution Prevention (LAP3), Department of Environmental Science & Engineering, Fudan University, Shanghai 200433, China. Electronic address:
Titanium dioxide nanoparticles (TiO NPs) can reduce sperm number, but the mechanisms of defective spermatogenesis induced by TiO NPs have not been studied through cell-cell interactions at present. A kind of biomimetic three-dimensional blood-testis barrier microfluidic chip capable of intercellular communication was constructed with soft lithography techniques, including Sertoli cell (TM4), spermatogonia (GC-1) and vascular endothelial cell units, to study the mechanisms of TiO NPs-induced defective spermatogenesis. TM4 and GC-1 cells cultured in TiO NPs exposure and control chips were collected for transcriptomics and metabonomics analysis, and key proteins and metabolites in changed biological processes were validated.
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