-Substituted naphthalene complexes (TripPn)Naph (Pn = Sb 1, Bi 2) were synthesised and their redox behaviour investigated. Oxidation of 1 with [Fc][BAr] (BAr = B(CF)) yielded [(TripSb)(TripSb)Naph][BAr] (3) containing the stibane-coordinated stibenium cation [(TripSb)(TripSb)Naph]. Subsequent reduction of 3 with KC yielded distibane (TripSb)Naph (4). 1-4 were characterised by NMR (H, C) and IR spectroscopy as well as single-crystal X-ray diffraction (sc-XRD), while their electronic structures were analysed by quantum chemical computations.
Download full-text PDF |
Source |
|---|---|
| http://dx.doi.org/10.1039/d2cc01986h | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Bisstibane-distibane conversion consecutive single-electron oxidation and reduction reaction.
Chem Commun (Camb)
June 2022
Institute of Inorganic Chemistry, University of Duisburg-Essen, 45117 Essen, Germany.
-Substituted naphthalene complexes (TripPn)Naph (Pn = Sb 1, Bi 2) were synthesised and their redox behaviour investigated. Oxidation of 1 with [Fc][BAr] (BAr = B(CF)) yielded [(TripSb)(TripSb)Naph][BAr] (3) containing the stibane-coordinated stibenium cation [(TripSb)(TripSb)Naph]. Subsequent reduction of 3 with KC yielded distibane (TripSb)Naph (4).
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!