A novel kind of star triptycene-based microporous polymer (STPs) was synthesized efficiently from trihalotriptycenes by nickel(0)-catalyzed Ullmann cross-coupling reactions. STPs display a BET surface area of 1305 m g and 1990 m g, and reversibly adsorb 1.60 and 1.93 wt % H at 1.0 bar/77 K, 16.15 and 18.20 wt % CO at 1.0 bar/273 K for and , respectively.
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