We exploit the effect of light-induced atomic desorption to produce high atomic densities (n≫k^{3}) in a rubidium vapor cell. An intense off-resonant laser is pulsed for roughly one nanosecond on a micrometer-sized sapphire-coated cell, which results in the desorption of atomic clouds from both internal surfaces. We probe the transient atomic density evolution by time-resolved absorption spectroscopy. With a temporal resolution of ≈ 1 ns, we measure the broadening and line shift of the atomic resonances. Both broadening and line shift are attributed to dipole-dipole interactions. This fast switching of the atomic density and dipolar interactions could be the basis for future quantum devices based on the excitation blockade.
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http://dx.doi.org/10.1103/PhysRevLett.128.173401 | DOI Listing |
ChemSusChem
December 2024
University of Rome La Sapienza, Department of Chemistry, P.le A. Moro 5, 00185, Rome, ITALY.
This work illustrates a physico-chemical study of the structural, dynamic, and transport properties of electrolytes made of LiTFSI solutions in sulphoxide and sulphone solvent mixtures. Experimental measurements, by Raman and NMR spectroscopies, as well as electrochemical impedance spectroscopy, reveal the formation of a variety of ionic aggregates depending on the solvent composition that significantly affect the ion mobility and conductivity of the electrolyte. Mixtures containing tetrahydrothiophene-1-oxide exhibit a larger ion mobility due to a rapid exchange mechanism between solvent molecules, whereas the use of tetramethylene sulphone favors the formation of ionic aggregates due to the strong dipolar interactions between solvent molecules.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Université Grenoble Alpes, Grenoble INP, CEA, IRIG, PHELIQS, 38000 Grenoble, France.
The antiferromagnetic structure of Yb_{3}Ga_{5}O_{12} is identified by neutron diffraction experiments below the previously known transition at T_{λ}=54 mK. The magnetic propagation vector is found to be k=(1/2,1/2,0), an unusual wave vector in the garnet structure. The associated complex magnetic structure highlights the role of exchange interactions in a nearly isotropic system dominated by dipolar interactions and finds echoes with exotic structures theoretically proposed.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
JILA, NIST, Department of Physics, University of Colorado, Boulder, Colorado 80309, USA.
We investigate the driven-dissipative dynamics of multilevel atomic arrays interacting via dipolar interactions at subwavelength spacings. Unlike two-level atoms in the weakly excited regime, multilevel atoms can become strongly entangled. The entanglement manifests as the growth of spin waves in the ground-state manifold and survives after turning off the drive.
View Article and Find Full Text PDFPhys Rev Lett
December 2024
Departament de Física, Campus Nord B4-B5, Universitat Politècnica de Catalunya, E-08034 Barcelona, Spain.
We predict that ultracold bosonic dipolar gases, confined within a multilayer geometry, may undergo self-assembling processes, leading to the formation of chain gases and solids. These dipolar chains, with dipoles aligned across different layers, emerge at low densities and resemble phases observed in liquid crystals, such as nematic and smectic phases. We calculate the phase diagram using quantum Monte Carlo methods, introducing a newly devised trial wave function designed for describing the chain gas, where dipoles from different layers form chains without in-plane long-range order.
View Article and Find Full Text PDFAnal Chem
December 2024
School of Biological Sciences, Nanyang Technological University, 60 Nanyang Drive, 637551 Singapore.
Although trifluoroacetic acid (TFA) is not typically considered a Hofmeister reagent, it has been demonstrated to modulate biocoacervation. We show that TFA can be employed to probe specific interactions in coacervating bioinspired peptide phenylalanine (Phe) F-labeled at a single site, altering its liquid-liquid phase separation (LLPS) behavior. Solid-state nuclear magnetic resonance (NMR) spectroscopy revealed two dynamically distinct binding modes of TFA with Phe, resulting in a structured, dipolar-ordered complex and a more dynamic complex, highlighting the proximity between TFA and Phe.
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