Differential mobility spectrometry coupled to mass spectrometry (DMS-MS) for the classification of Spanish PDO paprika.

Food Chem

Department of Chemical Engineering and Analytical Chemistry, University of Barcelona, Martí i Franquès 1-11, E08028 Barcelona, Spain; Research Institute in Food Nutrition and Food Safety, University of Barcelona, Av. Prat de la Riba 171, Edifici Recerca (Gaudí), E08921 Santa Coloma de Gramenet, Spain; Serra Húnter Fellow, Generalitat de Catalunya, Rambla de Catalunya 19-21, E08007 Barcelona, Spain. Electronic address:

Published: October 2022

AI Article Synopsis

  • Ion mobility spectrometry (IMS), specifically differential mobility spectrometry coupled with mass spectrometry (DMS-MS), shows promise in food analysis for classification and authentication.
  • This study focuses on using DMS-MS to analyze 70 Spanish paprika samples from different regions, employing advanced statistical methods like partial least squares regression-discriminant analysis (PLS-DA) and soft independent modeling of class analogy (SIMCA).
  • The results demonstrated successful classification based on geographical origin and high accuracy in authenticating La Vera and Mallorca paprika samples.

Article Abstract

Ion mobility spectrometry (IMS) has proved its huge potential in many research areas, especially when hyphenated with chromatographic techniques or mass spectrometry (MS). However, focusing on food analysis, and particularly in classification and authentication issues, very few applications have been reported. In this study, differential mobility spectrometry coupled to mass spectrometry (DMS-MS) is presented for the first time as an alternative and high-throughput technique for food classification and authentication purposes using a fingerprinting strategy. As a study case, 70 Spanish paprika samples (from La Vera, Murcia, and Mallorca) were analyzed by DMS-MS to address their classification -using partial least squares regression-discriminant analysis (PLS-DA)- and authentication -through soft independent modeling of class analogy (SIMCA). As a result, after external validation, complete sample classification according to their geographical origin and excellent La Vera and Mallorca sample authentication were reached.

Download full-text PDF

Source
http://dx.doi.org/10.1016/j.foodchem.2022.133141DOI Listing

Publication Analysis

Top Keywords

mobility spectrometry
12
mass spectrometry
12
differential mobility
8
spectrometry coupled
8
coupled mass
8
spectrometry dms-ms
8
classification authentication
8
spectrometry
6
classification
5
dms-ms classification
4

Similar Publications

This study presents the fabrication of a sustainable flexible humidity sensor utilizing chitosan derived from mealworm biomass as the primary sensing material. The chitosan-based humidity sensor was fabricated by casting chitosan and polyvinyl alcohol (PVA) films with interdigitated copper electrodes, forming a laminate composite suitable for real-time, resistive-type humidity detection. Comprehensive characterization of the chitosan film was performed using Fourier-transform infrared (FTIR) spectroscopy, contact angle measurements, and tensile testing, which confirmed its chemical structure, wettability, and mechanical stability.

View Article and Find Full Text PDF

Tellurium, recognized as one of the technology-critical elements, should be considered as a xenobiotic. Its application, i.a.

View Article and Find Full Text PDF

One of the main objectives of the ion mobility spectrometry (IMS) technique is to reduce moisture in detection systems, which causes the formation of ion clusters and ion water and a reduction in formed clusters' activity. Thus, one of the methods limiting moisture in a sampling injection system is to use hydrophobic polymeric membranes. The use of membranes with high permeability relative to the analysed organic compounds is required, including toxic agents in air (TAAs).

View Article and Find Full Text PDF

Dansyl labeling is a widely used approach for enhancing the detection of small molecules by UV spectroscopy and mass spectrometry. It has been successfully applied to identify and quantify a variety of biological and environmental specimens. Despite clear advantages, the dansylation reaction has found very few applications in the study of proteins.

View Article and Find Full Text PDF

Classification of Strawberry Maturity Stages and Varieties Using Neural Networks Based on Volatile Organic Compounds.

Foods

January 2025

College of Biosystems Engineering and Food Science, Key Laboratory of Agro-Products Postharvest Handling of Ministry of Agriculture and Rural Affairs, Zhejiang University, Hangzhou 310058, China.

Volatile organic compounds (VOCs) are closely associated with the maturity and variety of strawberries. However, the complexity of VOCs hinders their potential application in strawberry classification. This study developed a novel classification workflow using strawberry VOC profiles and machine learning (ML) models for precise fruit classification.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!