This paper reviews the advantages and disadvantages of the use of fertilizers obtained from leather waste, to ameliorate the agricultural soil quality. The use of leather waste (hides and skins) as raw materials to obtain biopolymer-based fertilizers is an excellent example of a circular economy. This allows the recovery of a large quantity of the tanning agent in the case of tanned wastes, as well as the valorization of significant quantities of waste that would be otherwise disposed of by landfilling. The composition of organic biopolymers obtained from leather waste is a rich source of macronutrients (nitrogen, calcium, magnesium, sodium, potassium), and micronutrients (boron, chloride, copper, iron, manganese, molybdenum, nickel and zinc), necessary to improve the composition of agricultural soils, and to remediate the degraded soils. This enhances plant growth ensuring better crops. The nutrient release tests have demonstrated that, by using the biofertilizers with collagen or with collagen cross-linked with synthetic polymers, the nutrient release can be controlled and slowed. In this case, the loss of nutrients by leaching into the inferior layers of the soil and ground water is minimized, avoiding groundwater contamination, especially with nitrate.
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http://dx.doi.org/10.3390/polym14091928 | DOI Listing |
Environ Sci Pollut Res Int
December 2024
Biochemical Conversion Division, Sardar Swaran Singh National Institute of Bio-Energy, Kapurthala, Punjab, 144 603, India.
The disposal of municipal solid waste (MSW) in urban areas is a big issue nowadays in most of the countries. Developing countries like India are struggling with the continuous indiscriminate disposal of MSW due to rapid increase in the urbanization, industrialization, and human population growth. The mismanagement of MSW causes adverse environmental impacts, public health risks, and other socio-economic problems.
View Article and Find Full Text PDFJ Hazard Mater
December 2024
College of Materials Science and Chemical Engineering, Harbin Engineering University, Harbin 150001, China; Nanhai Institute of Harbin Engineering University, Sanya 572024, China. Electronic address:
The rational use of solar energy to achieve photothermal conversion is an attractive strategy to promote the efficient removal of radioactive Cs and Sr from nuclear wastewater. Herein, a photothermal adsorbent of composite aerogel with three-dimensional porous structure is fabricated by integrating prussian blue analogues (PBAs) and straw biochar into the chitosan (CS) and waste leather scrap hydrolysate (WLSH) aerogel matrix (CS/WLSH/C/PBAs). The local heating effect generated by CS/WLSH/C/PBAs aerogel induce to generate steam, accelerating the enrichment of Cs and Sr in the solution, which increase their interaction with the CS/WLSH/C/PBAs and improves their adsorption rates and capacities.
View Article and Find Full Text PDFMaterials (Basel)
November 2024
Department of Physical Aspects of Ecoenergy, The Institute of Fluid-Flow Machinery Polish Academy of Sciences, Fiszera 14 St., 80-231 Gdańsk, Poland.
Leather waste contains up to 10% nitrogen (N); thus, combustion or gasification only for the energy recovery would not be rational, if safety standards are met. On the other hand, the chromium (Cr) content exceeding 5% in half of the waste stream (/) is too significant to be applied in agriculture. In this work, four acid hydrolysates from leather waste shavings, both wet-white free of Cr and wet-blue with Cr, were used: two with a mixture of acids and supplemented with Cu, Mn, and Zn, and the other two as semi-products from collagen extraction using hydrochloric acid.
View Article and Find Full Text PDFBiomacromolecules
December 2024
College of Bioresources Chemical and Materials Engineering (College of Flexible Electronics), Shaanxi University of Science & Technology, Xi'an 710021, China.
The development of engineered hydrogels with high strength, self-recovery, and adhesion is essential for applications requiring resistance to large deformations and cyclic loading. Herein, a triple-network (TN) hydrogel with ultrahigh compressive strength, strong adhesion, and good self-recovery was constructed by using tannic acid-modified chrome leather scrap hydrolysate as the first network, polyacrylamide as the second network, and poly-2-propenamide-2-methylpropanesulfonic acid as the third network. The ultrahigh (70 MPa compressive strength and 95% compression deformation) TN hydrogels were effectively created, which is attributed to the synergy of the three networks.
View Article and Find Full Text PDFBiodegradation
December 2024
Department of Environmental Engineering, Middle East Technical University, 06800, Ankara, Turkey.
This study focused on a new approach for valorization of both ground tire rubber (GTR) and nitrate-containing wastewater via simultaneous devulcanization and denitrification. Initially, sulfur-based autotrophic denitrifiers were successfully enriched from three different seed sludge sources, biological nutrient removal (BNR) sludge, anaerobic digester sludge and BNR sludge of a leather organized industrial zone WWTP. Average nitrate removal efficiencies were 96-98%.
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