In the current work, the reactions of [60]fullerene with alkynes promoted by OH (base) are addressed. The treatment of C with alkynes in the presence of TBAOH produces alkynylation products (R-C-H) with high selectivity in -DCB at 100 °C. Plausible reaction mechanisms were proposed. This work provides a convenient and environmental friendly method for the functionalization of fullerenes.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9087709 | PMC |
| http://dx.doi.org/10.1039/d2ra01300b | DOI Listing |
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