The title compound, 2CHNO·HO, crystallizes in the monoclinic 2/ space group with two independent mol-ecules ( and ) in the asymmetric unit. In the crystal, mol-ecules and are linked through the water mol-ecules by inter-molecular O-H⋯O and O-H⋯N hydrogen bonds, producing chains along the -axis direction. These chains are linked with neighboring chains parallel to the (103) plane C-H⋯π inter-actions, generating ribbons along the -axis direction. The stability of the mol-ecular packaging is ensured by van der Waals inter-actions between the ribbons. According to the Hirshfeld surface study, H⋯H inter-actions are the most significant contributors to the crystal packing (80.3% for mol-ecule and 84.8% for mol-ecule ).

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9069515PMC
http://dx.doi.org/10.1107/S2056989022004297DOI Listing

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