AI Article Synopsis
- The study explored a method for chloride-bromide halogen exchange using a supported molten alkyl phosphonium catalyst, reacting alkyl chlorides and bromides.
- The reaction reached near equilibrium under specific conditions in a tubular flow reactor at 150 °C and 1500 GHSV.
- The catalyst, made through the impregnation of alumina or silica, demonstrated high stability over extended periods, and a potential catalytic cycle pathway was suggested.
Article Abstract
Chloride-bromide halogen exchange was realized when a mixture of an alkyl chloride and an alkyl bromide were reacted over a supported molten alkyl phosphonium catalyst. Conversion was found to be near equilibrium in a tubular flow reactor at 150 °C and 1500 GHSV. The catalyst was prepared by impregnation of alumina or silica support and found to be highly stable for relatively long periods of time. A pathway for the catalytic cycle is proposed.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9077571 | PMC |
| http://dx.doi.org/10.1039/c7ra12579h | DOI Listing |
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