As a result of extensive research efforts by several research groups, magnetite-based materials have gained enormous attention in diverse fields including biomedicine, catalysis, energy and data storage devices, magnetic resonance imaging, and environmental remediation. Owing to their low production cost, ease of modification, biocompatibility, and superparamagnetism, the use of these materials for the abatement of environmental toxicants has been increasing continuously. Here we focus on the recent advances in the use of magnetite-based adsorbents for removal of radionuclides (such as Cs(i), Eu(iii), Sr(ii), U(vi), ) from diverse aqueous phases. This review summarizes the preparation and surface modification of magnetite-based adsorbents, their physicochemical properties, adsorption behavior and mechanism, and diverse conventional and recent environmental technological options for the treatment of water contaminated with radionuclides. In addition, case studies for the removal of radionuclides from actual contaminated sites are discussed, and finally the optimization of magnetite-based remedial solutions is presented for practical application.
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http://dx.doi.org/10.1039/c7ra12299c | DOI Listing |
Environ Res
January 2025
School of Environmental Science and Engineering, Guangdong University of Technology, Guangzhou, 510006, China.
Using magnetite-based nanocomposite adsorbents to remove and recycle phosphate from wastewater is crucial for controlling eutrophication and ensuring the sustainable use of phosphorus resources. However, the weak structural stability between magnetite and adsorptive nanoparticles often reduces phosphate removal efficiency in real-world applications. This instability primarily results from the loss of adsorptive nanoparticles from the magnetite surfaces, particularly when metal oxide nanoparticles are used for phosphate removal and recycling.
View Article and Find Full Text PDFChemosphere
November 2024
Materials Research Centre, Malaviya National Institute of Technology Jaipur, Jaipur, 302017, India; Department of Chemistry, Malaviya National Institute of Technology Jaipur, Jaipur, 302017, India. Electronic address:
Nuclear waste management is a crucial aspect as the most significant threat to the ecosystem is caused by radioactive waste in which thorium contamination remains a prominent issue. This work represents an integrated approach for the elimination of thorium through the adsorption technique and subsequent electrochemical sensing using Magnetite@Graphene Oxide@Chitosan (M@GO@Cs). Moreover, the sorption of Th(IV) ions is optimized through batch studies, which are consistent with the results derived from ANOVA using the Box-Behnken Design model, and the ideal parameters resulted in 95.
View Article and Find Full Text PDFSci Total Environ
January 2020
School of Environmental Science and Engineering, Guangzhou University, Guangzhou 510006, China; Linköping University - Guangzhou University Research Center on Urban Sustainable Development, Guangzhou University, China. Electronic address:
The development of efficient and regenerable adsorbent coupled with advanced oxidation for enhanced thallium (Tl) removal has been a recent focus on wastewater treatment. In this study, a magnetite-based biochar derived from watermelon rinds was synthesized and used as a sustainable adsorbent and catalyst for hypochlorite oxidation and removal of Tl(I) from wastewater. The addition of hypochlorite substantially enhanced the Tl(I) removal under normal pH range (6-9).
View Article and Find Full Text PDFEnviron Sci Pollut Res Int
August 2019
Department of Environmental Sciences and Engineering Government College University, Faisalabad, Pakistan.
The present study aims at evaluating the batch scale potential of cotton shell powder (CSP), Moringa oleifera leaves (ML), and magnetite-assisted composites of Moringa oleifera leaves (MLMC) and cotton shell powder (CSPMC) for the removal of brilliant green dye (BG) from synthetic wastewater. This is the first attempt to combine biosorbents with nanoparticles (NPs) for the removal of BG. The surface properties of ML, CSP, and their composites were characterized with Fourier-transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), and energy-dispersive X-ray (EDX).
View Article and Find Full Text PDFWater Res
August 2019
Departament of Chemical, Biological and Environmental Engineering, Escola d'Enginyeria, Universitat Autònoma de Barcelona, 08193, Bellaterra, Spain.
A novel approach for harvesting Scenedesmus sp. microalgae from real wastewater by using adsorbents of magnetite-based nanoparticles (FeO NPs) was tested in this study for the first time for this microalgae. Using these NPs, the harvesting efficiency was even higher than 95%.
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