β-GaO, a semiconductor material, has attracted considerable attention given its potential applications in high-power devices, such as high-performance field-effect transistors. For decades, β-GaO has been processed through chemical mechanical polishing (CMP). Nevertheless, the understanding of the effect of OH on β-GaO processed through CMP with an alkaline slurry remains limited. In this study, β-GaO substrates were successively subjected to mechanical polishing (MP), CMP and etching. Then, to investigate the changes that occurred on the surfaces of the samples, samples were characterised through atomic force microscopy (AFM), three-dimensional laser scanning confocal microscopy (LSCM), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). LSCM and SEM results showed that β-GaO is highly vulnerable to brittle fracture during MP. AFM revealed that an ultrasmooth and nondamaged surface with a low of approximately 0.18 nm could be obtained through CMP. XPS results indicated that a metamorphic layer, which mainly contains soluble gallium salt (Ga(OH) ), formed on the β-GaO surface through a chemical reaction. A dendritic pattern appeared on the surface of β-GaO after chemical etching. This phenomenon indicated that the chemical reaction on the β-GaO surface occurred in a nonuniform and selective manner. The results of this study will aid the optimization of slurry preparation and CMP.
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http://dx.doi.org/10.1039/c7ra11570a | DOI Listing |
Materials (Basel)
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Faculty of Mechanical Engineering, Institute of Mechanical Technology, Poznan University of Technology, Piotrowo 3, 60-695 Poznan, Poland.
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View Article and Find Full Text PDFNanomaterials (Basel)
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School of Artificial Intelligence, Optics and Electronics (iOPEN), Northwestern Polytechnical University, Xi'an 710072, China.
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Federal University of Uberlândia, Chemistry Institute, Uberlândia, MG, 38400-902, Brazil.
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December 2024
Department of Chemistry, University of Hannam, Daejeon 34430, Republic of Korea.
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College of Mechanical Engineering, Zhejiang University of Technology, Hangzhou 310023, China.
Shear-thickening fluid (STF) is widely applied in various practical engineering fields due to its rheological properties of increased viscosity under load. We investigated the integration of STF with fiber brushes to prepare a novel composite material for polishing applications. The impact of composite material properties is studied in surface finish, specifically roughness and morphology, across flat and uneven surfaces.
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