Mesoporous carbon materials have recently attracted immense research interest because of their potential application in water purification fields. Herein, we report the synthesis of a mesoporous carbon sponge (MCS) from a supramolecular microcrystalline cellulose-polymer system triggered by microwave-assisted treatment. Benefiting from the three-dimensional (3D) interconnected mesopores and an evenly distributed ball-like protuberance on the inner surfaces of the macropores, the MCS exhibited a high adsorption capacity (93.96 mg g) for fast Cr(vi) removal within 5 min. Additionally, the MCS can be regenerated and reused after the adsorption-desorption process, and maintained an adsorption capacity of ∼86% after 10 cycles. The high adsorption capacity, significantly reduced treatment time, and reusability make the MCS promising for the purification of wastewater on a large scale.
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http://dx.doi.org/10.1039/c8ra00012c | DOI Listing |
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January 2025
Institute of Smart City and Intelligent Transportation, Southwest Jiaotong University, Chengdu, 610031, China.
Although carbon-based supercapacitors (SCs) hold the advantages of high-power and large-current characteristics, they are difficult to realize ultrahigh-power density (> 200 kW kg) and maintain almost constant energy density at ultrahigh power. This limitation is mainly due to the difficulty in balancing the structural order related to the electrical conductivity of carbon materials and the structural disorder related to the pore structure. Herein, we design a novel super-structured tubular carbon (SSTC) with a crosslinked porous conductive network to solve the structure order-disorder tradeoff effect in carbon materials.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
School of Chemistry and Chemical Engineering, Guangxi Key Laboratory of Petrochemical Resource Processing and Process Intensification Technology, Guangxi University (GXU), 100 Daxuedong Road, Xixiangtang District, Nanning 530004 China. Electronic address:
Porous carbons with large surface area (>3000 m/g) and heteroatom dopants have shown great promise as electrode materials for zinc ion hybrid capacitors. Centralized mesopores are effective to accelerate kinetics, and edge nitrogen can efficiently enhance pseudocapacitive capability. It is a great challenge to engineer centralized mesopores and edge nitrogen in large-surface-area porous carbons.
View Article and Find Full Text PDFMaterials (Basel)
January 2025
Departamento de Química Orgánica, Universidad de Zaragoza, 50009 Zaragoza, Spain.
Dye-sensitization is a promising strategy to improve the light absorption and photoactivity abilities of wide-bandgap semiconductors, like TiO. For effective water-splitting photoanodes with no sacrificial agents, the electrochemical potential of the dye must exceed the thermodynamic threshold needed for the oxygen evolution reaction. This study investigates two promising organic cyanoacrylic dyes, designed to meet that criterion by means of theoretical calculations.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
Graduate School of Energy Convergence, Institute of Integrated Technology, Gwangju Institute of Science and Technology, Gwangju 61005, Republic of Korea.
Zeolitic imidazolate framework-8 (ZIF-8) has been extensively studied as a precursor for nitrogen-doped carbon (NC) materials due to its high surface area, tunable porosity, and adjustable nitrogen content. However, the intrinsic microporous structure of the ZIF-8 limits mass transport and accessibility of reactants to active sites, reducing its effectiveness in electrochemical applications. In this study, a soft templating approach using a triblock copolymer was used to prepare mesoporous ZIF-8-derived NC (Meso-ZIF-NC) samples.
View Article and Find Full Text PDFNanomaterials (Basel)
January 2025
Center for Sustainable Future Technologies @POLITO, Istituto Italiano di Tecnologia, Via Livorno 60, 10144 Turin, Italy.
The electrochemical reduction of CO (CORR) to value-added products has garnered significant interest as a sustainable solution to mitigate CO emissions and harness renewable energy sources. Among CORR products, formic acid/formate (HCOOH/HCOO) is particularly attractive due to its industrial relevance, high energy density, and potential candidate as a liquid hydrogen carrier. This study investigates the influence of the initial oxidation state of tin on CORR performance using nanostructured SnO catalysts.
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