Novel donor-acceptor dyads containing [2.2]- and [3.3]paracyclophane (PCP) as the bridging moiety were synthesized and used to effectively fabricate dye-sensitized hydrogen production systems. All the prepared compounds had a phenothiazine and a cyanoacrylic acid/pyridinyl acrylonitrile moiety acting as an electron donor and acceptor, respectively. Although cyclic voltammetry measurements showed similar electron-donating properties among all the synthesized dyads, the lowest absorption energy of the [2.2]PCP moiety was lower than that of the [3.3]PCP one; this was due to its shorter distance between benzene rings, which could effectively drive the charge transfer between the donor and acceptor chromophores. Under visible light (>395 nm), a dyad-loaded photocatalyst in a 0.5 M aqueous glycerol solution generated detectable hydrogen gases. The optimal turnover number and photocurrent order exhibited the same trend as the hydrogen production rate since the suggested number of excited photons played a critical role in hydrogen production.

Download full-text PDF

Source
http://dx.doi.org/10.1002/chem.202200790DOI Listing

Publication Analysis

Top Keywords

hydrogen production
16
[22]- [33]paracyclophane
8
dye-sensitized hydrogen
8
donor acceptor
8
hydrogen
5
[33]paracyclophane bridging
4
bridging units
4
units organic
4
organic dyads
4
dyads visible-light-driven
4

Similar Publications

Drug-Phospholipid Co-Amorphous Formulations: The Role of Preparation Methods and Phospholipid Selection.

Pharmaceutics

December 2024

Department of Pharmacy, Faculty of Health and Medical Science, University of Copenhagen, Universitetsparken 2, DK-2100 Copenhagen, Denmark.

: This study aims to broaden the knowledge on co-amorphous phospholipid systems (CAPSs) by exploring the formation of CAPSs with a broader range of poorly water-soluble drugs, celecoxib (CCX), furosemide (FUR), nilotinib (NIL), and ritonavir (RIT), combined with amphiphilic phospholipids (PLs), including soybean phosphatidylcholine (SPC), hydrogenated phosphatidylcholine (HPC), and mono-acyl phosphatidylcholine (MAPC). : The CAPSs were initially prepared at equimolar drug-to-phospholipid (PL) ratios by mechano-chemical activation-based, melt-based, and solvent-based preparation methods, i.e.

View Article and Find Full Text PDF

Hydrogen, as a zero-emission fuel, produces only water when used in fuel cells, making it a vital contributor to reducing greenhouse gas emissions across industries like transportation, energy, and manufacturing. Efficient hydrogen storage requires lightweight, high-strength vessels capable of withstanding high pressures to ensure the safe and reliable delivery of clean energy for various applications. Type V composite pressure vessels (CPVs) have emerged as a preferred solution due to their superior properties, thus this study aims to predict the performance of a Type V CPV by developing its numerical model and calculating numerical burst pressure (NBP).

View Article and Find Full Text PDF

Rubber is widely used in situations involving cyclic loads, and the influence of temperature on rubber properties is particularly pronounced under cyclic loading. In this study, mechanical property tests and crack propagation tests of carbon black-filled hydrogenated nitrile butadiene rubber were conducted at four different operating temperatures. Based on the results of the crack propagation tests, the temperature-dependent characteristics of the Paris-Erdogan parameters and strain energy density were clarified.

View Article and Find Full Text PDF

Bimetallic NiCr nanoparticles decorated on carbon nanofibers (NiCr@CNFs) were synthesized through electrospinning and investigated as catalysts for hydrogen generation from the dehydrogenation of sodium borohydride (SBH). Four distinct compositions were prepared, with chromium content in the catalysts ranging from 5 to 25 weight percentage (wt%). Comprehensive characterization confirmed the successful formation of bimetallic NiCr@CNFs.

View Article and Find Full Text PDF

Drought is an abiotic disturbance that reduces photosynthesis, plant growth, and crop yield. Ascorbic acid (AsA) was utilized as a seed preconditioning agent to assist broccoli ( var. ) in resisting drought.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!