Palygorskite-anchored Pd complexes catalyze the coupling reactions of pyrimidin-2-yl sulfonates.

RSC Adv

Key Laboratory for Utility of Environment-Friendly Composite Materials and Biomass in Universities of Gansu Province, College of Chemical Engineering, Northwest Minzu University Lanzhou Gansu 730030 People's Republic of China.

Published: September 2019

AI Article Synopsis

  • A new anchored palladium complex (PGS-APTES-Pd(OAc)) was created using natural clay mineral palygorskite, and it was thoroughly analyzed with various techniques like XPS and XRD.
  • This complex served as an effective catalyst for coupling reactions involving pyrimidin-2-yl sulfonates, showcasing its utility in organic synthesis.
  • The catalyst demonstrated high stability and can be reused without activation, making it an environmentally friendly option for chemical reactions.

Article Abstract

In this work, an anchored Pd complex (PGS-APTES-Pd(OAc)) was prepared simple and green steps from the natural clay mineral palygorskite and was well characterized by XPS, XRD, IR, SEM, and EDX. This complex was further utilized as a fine catalyst for the C-C/C-N coupling reactions of pyrimidin-2-yl sulfonates. Subsequently, the cyclic utilization test indicated the high stability and sustainability of this PGS-APTES-Pd(OAc) catalyst, and no activation was required in the recycling process, providing an applicable and reusable catalyst in organic synthesis.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9072395PMC
http://dx.doi.org/10.1039/c9ra06035aDOI Listing

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