A liquid crystal laser using a polymer-stabilized simple cubic blue phase (BPII) platform has been scarcely reported because the polymer stabilization of a BPII is relatively difficult compared to that of a body-centered-cubic BP (BPI). In this study, we succeeded in fabricating a dye-doped polymer-stabilized BPII laser with wide operating-temperature ranges over 15 °C including room temperature. A narrow and sharp single laser peak with a full width at half maximum of approximately 2 nm was derived from the photonic band edge effect of the BPII-distributed feedback optical resonator. As a result, the laser emission was a circularly polarized light, which matched the chirality of the proposed pure BPII.
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http://dx.doi.org/10.1039/c9ra07460k | DOI Listing |
Nat Commun
December 2024
School of Materials Science and Engineering, East China University of Science and Technology, Shanghai, China.
Liquid crystal elastomers (LCEs) with various deformation properties based on phase transition were widely used as actuators and provided potential to fabricate functional surfaces with tunable microstructure. Herein, we demonstrate a strategy to fabricate dynamic micro wrinkles on LCE surfaces based on LC phase transition. Stable micron-sized surface wrinkles on the anthracene-containing LCE film (AnLCE) are fabricated by ultraviolet exposure induced gradient cross-linking and subsequently stretching-releasing (UV-SR).
View Article and Find Full Text PDFSmall
December 2024
Département de chimie, Université de Sherbrooke, Sherbrooke, QC, J1K 2R1, Canada.
A liquid crystal elastomer (LCE) actuator capable of colorimetric humidity sensing is realized. The designed LCE features acid protonated amino azobenzene side groups in its structure, which endow the actuator with the hygroscopicity and act as the humidity reporter via color changes. Given that the protonated and deprotonated chromophore absorb visible light at different wavelengths, when the protonated LCE is under higher humidity, it absorbs more water that deprotonates azobenzene and leads to a change in color.
View Article and Find Full Text PDFSmall Methods
December 2024
Institute of Translational Medicine, Nanjing Drum Tower Hospital, School of Biological Science and Medical Engineering, Southeast University, Nanjing, 210096, China.
Colored contact lenses have gained popularity among young individuals owing to their ability to alter the appearance of the wearer's eyes. However, conventional lenses containing chemical dyes are susceptible to detachment of the pigment layer, which can lead to corneal damage. In this research, a novel cellulose-based structural color contact lens (SCCL) is presented that enhances aesthetic appeal via a cholesteric liquid crystal (CLC) layer.
View Article and Find Full Text PDFFront Microbiol
December 2024
Department of Public Health, University of Naples Federico II, Naples, Italy.
Introduction: The persistence of in the contaminated environment is sustained by tolerance to biocides and ability to growth as biofilm. The aim of the study was to analyze the susceptibility of biofilms to chlorhexidine (CHX) and benzalkonium (BZK) biocides and the ability of natural monomeric stilbenoid resveratrol (RV) to modulate the phenomenon.
Methods: Biofilm formation and preformed biofilm were tested by Crystal violet and tetrazolium salt reduction assay, respectively.
J Colloid Interface Sci
December 2024
Institute for Frontier Materials, Deakin University, Geelong VIC 3216, Australia. Electronic address:
Hypothesis: Optimizing interfacial positioning of crosslinkers within a reactive self-assembled hexagonal lyotropic liquid crystals (HLLC) system could assist in retaining the hexagonal structure during polymerization and thereby improving water filtration performances of the as-synthesized nanofiltration membranes.
Experiments: The positioning of the hydrophilic crosslinker, poly (ethylene glycol) diacrylate (PEGDA), within the reactive HLLC system was systematically investigated using H and C solid nuclear magnetic resonance (NMR) and small angle X-ray scattering (SAXS) techniques. The structural variation and water filtration performances of these HLLC systems with/without crosslinkers after polymerization were further studied using grazing incidence SAXS (GISAXS) and crossflow filtration tests, respectively.
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