Ultrathin nickel-metal-organic framework (Ni-MOF) nanobelts, [Ni(CHO)(HO)]·40HO (Ni-MIL-77), have been exploited successfully for the fabrication of a non-enzymatic urea sensor. Ni-MOF ultrathin nanobelts in alkaline media can be used as an efficient catalyst for urea electrooxidation. As a non-enzymatic urea sensor, Ni-MOF ultrathin nanobelts exhibit a high sensitivity of 118.77 μA mM cm, wide linear range of 0.01-7.0 mM, and low detection limit of 2.23 μM (S/N = 3). The selectivity, stability and reliability of ultrathin Ni-MOF nanobelts towards urea oxidation are also investigated. Moreover, Ni-MOF ultrathin nanobelts were further used to detect urea in human body fluids. All these findings confirm that the urea sensor based on Ni-MOF ultrathin nanobelts is successfully prepared and promising for applications in medical diagnostics and environmental monitoring.
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http://dx.doi.org/10.1039/c9ra05716a | DOI Listing |
J Colloid Interface Sci
January 2025
Institute of Micro/Nano Materials and Devices, Ningbo University of Technology, Ningbo 315211 PR China. Electronic address:
The development of efficient photocatalysts inspired by natural photosynthesis has drawn considerable interest for sustainable hydrogen (H) production. Among the various strategies for enhancing H evolution, constructing step-scheme (S-scheme) heterojunctions has attracted extensive interest, thanks to their limited charge recombination and enhanced charge transport in comparison to the traditional photocatalytic systems. Herein, we report the engineering of a novel S-scheme heterojunction by integrating ultrathin ZnInS (ZIS) nanosheets with MOF-derived N-doped NiO porous microrods (ZIS/N-NiO) toward superior photocatalytic behaviors.
View Article and Find Full Text PDFJ Colloid Interface Sci
January 2025
State Key Laboratory of New Pharmaceutical Preparations and Excipients, Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of the Ministry of Education, Key Laboratory of Analytical Science and Technology of Hebei Province, School of Eco-Environment, College of Chemistry and Materials Science, Hebei University, 071002 Baoding, PR China. Electronic address:
In this study, we synthesized novel three-dimensional (3D) cross-flowered Co-Ni metal-organic framework (Co-Ni-MOF) precursors using the chemical precipitation method. Subsequently, we obtained Co-Ni-Fe layered double hydroxides (Co-Ni-Fe-LDHs) through an ion exchange strategy, which preserved their original morphology while consisting of ultrathin layered hydroxide nanosheets. The interlayer spacing of the LDH lamellar structure was finely tuned by varying the ratios of Co to Ni.
View Article and Find Full Text PDFACS Appl Mater Interfaces
June 2024
College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, Shaanxi, P. R. China.
Metal-organic frameworks (MOFs) have attracted attention due to their designable structures. However, recently reported MOF microwave-absorbing materials (MAMs) are dominated by powders. It remains a challenge to design MOF/carbon nanotube (CNT) composite structures that combine the mechanical properties of self-supporting flexibility with excellent microwave absorption.
View Article and Find Full Text PDFJ Colloid Interface Sci
September 2024
Hubei Key Laboratory of Catalysis and Materials Science, School of Chemistry and Materials Science, South-Central Minzu University, Wuhan 430074, PR China. Electronic address:
In this study, a directional loading of cadmium sulfide (CdS) nanoparticles (NPs) was achieved on the opposite edges of nickel metal-organic framework (Ni-MOF) nanosheets (NSs) by adjusting the weight ratio of CdS NPs in the reaction process to produce effective visible light photocatalysts. The close contact between the zero-dimensional (0D) and two-dimensional (2D) regions and the matching positions of the bands promoted charge separation and heterojunction formation. The optimal CdS NPs loading of composite material was 40 wt%.
View Article and Find Full Text PDFAngew Chem Int Ed Engl
July 2024
School of Chemistry and Chemical Engineering, Xi'an Key Laboratory of Functional Organic Porous Materials, Northwestern Polytechnical University, Xi'an, 710072, P. R. China.
Interfacial engineering of synergistic catalysts is one of the keys to achieving multiple proton-coupled electron transfer processes in nitrate-to-ammonia conversion. Herein, by joining ultrathin nickel-based metal-organic framework (denoted Ni-MOF) nanosheets with few-layered hydrogen-substituted graphdiyne-supported copper single atoms and clusters (denoted HsGDY@Cu), a tandem catalyst of Ni-MOFs@HsGDY@Cu with dual-active interfaces was developed for the concerted catalysis of nitrate-to-ammonia. In such a system, the sandwiched HsGDY layer could serve as a bridge to connect the coordinated unsaturated Ni sites with Cu single atoms/clusters in a limited range of 0 to 3.
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