Although nanoparticles, nanorods, and nanosheets of α-FeO on graphene sheets have been synthesized, it remains a challenge to grow 3D α-FeO nanomaterials with more sophisticated compositions and structures on the graphene sheets. Herein, we demonstrate a facile solvothermal route under controlled conditions to successfully fabricate 3D α-FeO hollow meso-microspheres on the graphene sheets (α-FeO/RGO HMM). Attributed to the combination of the catalytic features of α-FeO hollow meso-microspheres and the high conductivity of graphene, α-FeO/RGO HMM exhibited promising electrocatalytic performance as a counter electrode in dye-sensitized solar cells (DSSCs). The DSSCs fabricated with α-FeO HMM displayed high power conversion efficiency of 7.28%, which is comparable with that of Pt (7.71%).
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http://dx.doi.org/10.1039/c9ra02586c | DOI Listing |
J Chem Theory Comput
January 2025
Mechanical and Industrial Engineering Department, Northeastern University, Boston, Massachusetts 02115, United States.
Molecular dynamics is a popular method for evaluating the tensile stress behaviors of many nanomaterials; however, few manuscripts include their thermostat and barostat damping parameters along with their methods. Here, we illustrate the demonstrable effect that barostat integration has on system dynamics during uniaxial testing under a Nosé-Hoover scheme. Three systems are tested: a 2D graphene sheet, a 3D continuous aluminum volume, and a 3D discontinuous polyvinyl alcohol volume.
View Article and Find Full Text PDFJ Phys Chem Lett
December 2024
Biomolecular Physics Department, Faculty of Physics, Babeş-Bolyai University, 1 M. Kogalniceanu Str., 400084 Cluj-Napoca, Romania.
Surface-enhanced Raman spectroscopy (SERS) has emerged as a powerful tool for analyzing nucleic acids due to its exceptional sensitivity and specificity. This study rigorously investigates not only the impact of polyA strands of different lengths (, 5, 10, 15, and 20 adenine bases) but also their distinct grafting strategy (SH at 5' and NH at 5' end) on the SERS signal of DNA strand using synthesized gold nanoparticles (AuNPs) on graphene oxide sheets (GO-AuNPs). By comparing the thiol vs amine bonding onto the GO-AuNP nanoplatform, we found a strong correlation between the adenine peak intensity at 732 cm and the strand length for both grafting methods (SH at 5' end or NH at 5' end).
View Article and Find Full Text PDFNat Commun
December 2024
Department of Chemical Engineering, The University of Melbourne, Parkville, Victoria, Australia.
Colloidal properties of nanoparticles are intricately linked to their morphology. Traditionally, achieving high-concentration dispersions of two-dimensional (2D) nanosheets has proven challenging as they tend to agglomerate or re-stack under increased surface contact and Van der Waals attraction. Here, we unveil an excluded volume effect enabled by 2D morphology, which can be coupled with electrostatic repulsion to synthesize high-concentration aqueous graphene dispersions.
View Article and Find Full Text PDFAdv Sci (Weinh)
December 2024
Institute for Frontier Materials, Deakin University, Geelong, Victoria, 3220, Australia.
Two-dimensional (2D) nanochannels have demonstrated outstanding performance for sieving specific molecules or ions, owing to their uniform molecular channel sizes and interlayer physical/chemical properties. However, controllably tuning nanochannel spaces with specific sizes and simultaneously achieving high mechanical strength remain the main challenges. In this work, the inter-sheet gallery d-spacing of graphene oxide (GO) membrane is successfully tailored with high mechanical strength via a general radical-induced polymerization strategy.
View Article and Find Full Text PDFSci Rep
December 2024
Department of Electronics, Carleton University, Ottawa, ON, K1S 5B6, Canada.
In this paper, we propose a novel structure of anisotropic graphene-based hyperbolic metamaterial (AGHMM) sandwiched as a defect between two one-dimensional photonic crystals (PCs) in the terahertz (THz) region. The proposed structure is numerically simulated and analyzed using the transfer matrix method, effective medium theory and three-dimensional finite-difference time-domain. The defect layer of AGHMM consists of graphene sheets separated by subwavelength dielectric spacers.
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