A transfer hydrosilylation of ketones employing silyl formates as hydrosilane surrogates under mild conditions is presented. A total of 24 examples of ketones have been successfully converted to their corresponding silyl ethers with 61-99% yields in the presence of a PNP-based ruthenium catalyst and silyl formate reagent. The crucial role of the ligand for the transformation is demonstrated.
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Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9476892 | PMC |
| http://dx.doi.org/10.1039/d2cc00666a | DOI Listing |
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