The effect of the oxygen evolution reaction (OER) is important in water splitting. In this work, we develop sphere-like morphology spinel oxide CoFeO/NF by hydrothermal reaction and calcination, and the diameter of the spheres is about 111.1 nm. The CoFeO/NF catalyst exhibits excellent electrocatalytic performance with an overpotential of 273 mV at a current density of 10 mA cm and a Tafel slope of 78 mV dec. The cycling stability of CoFeO/NF is remarkable, and it only increased by 5 mV at a current density of 100 mA cm after 3000 cycles. Therefore, this simple method to prepare CoFeO/NF can enhance the OER properties of electrocatalysts, which makes CoFeO/NF a promising material to replace noble metal-based catalysts for the oxygen evolution reaction.
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http://dx.doi.org/10.1039/c9ra01802f | DOI Listing |
Phys Chem Chem Phys
January 2025
School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, P. R. China.
Electrocatalytic oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA) is a promising alternative for oxygen evolution reactions. The search for efficient catalysts has been attracting increasing scientific attention. This work explores the performance of nitrogen-doped graphene-supported single-atom catalysts (M-NC SACs) for the reaction.
View Article and Find Full Text PDFFront Mol Biosci
January 2025
Vienna Metabolomics Center (VIME), University of Vienna, Vienna, Austria.
Cancer is ranked as the top cause of premature mortality. Volatile organic compounds (VOCs) are produced from catalytic peroxidation by reactive oxygen species (ROS) and have become a highly attractive non-invasive cancer screening approach. For future clinical applications, however, the correlation between cancer hallmarks and cancer-specific VOCs requires further study.
View Article and Find Full Text PDFEnergy Fuels
January 2025
Department of Gaseous Electronics (F6), Jožef Stefan Institute, Jamova cesta 39, 1000 Ljubljana, Slovenia.
The production, conversion and storage of energy based on electrocatalysis, mainly assisted by oxygen evolution reaction (OER), plays a crucial role in alkaline water electrolyzers (AWEs) and fuel cells. Nevertheless, the insufficient availability of highly efficient catalyst materials at a reasonable cost that overcome the sluggish electrochemical kinetics of the OER is one of the significant obstacles. Herein, we report a fast and facile synthesis of vapor phase deposition of dual-phase nickel sulfide (Ni-sulfide) using low-temperature annealing in the presence of HS and demonstrated as an efficient catalyst for OER to address the issues with sluggish electrochemical kinetics.
View Article and Find Full Text PDFJ Phys Chem C Nanomater Interfaces
January 2025
Department of Chemistry and Biochemistry, San Francisco State University, 1600 Holloway Ave., San Francisco, California 94132, United States.
Water electrolysis is a green method of storing electrical energy in the chemical bonds of high-energy hydrogen gas (H). However, the anodic oxygen evolution reaction (OER) requires a significant kinetic overpotential, limiting the electrolysis rate. Recently, plasmonic gold nanoparticles (Au NPs) have been introduced to improve charge transfer at the interface between the OER electrocatalysts and the electrolyte under light illumination.
View Article and Find Full Text PDFACS Appl Mater Interfaces
January 2025
National Energy Metal Resources and New Materials Key Laboratory, Engineering Research Center of the Ministry of Education for Advanced Battery Materials, Hunan Provincial Key Laboratory of Nonferrous Value-Added Metallurgy, School of Metallurgy and Environment, Central South University, Changsha 410083, P. R. China.
Rechargeable Zn-air batteries (RZABs) are poised for industrial application, yet they require low-cost, high-performance catalysts that efficiently facilitate both the oxygen reduction reaction (ORR) and the oxygen evolution reaction (OER). The pivotal challenge lies in designing multimetal active sites and optimizing the carbon skeleton structure to modulate catalyst activity. In this study, we introduce a novel hierarchical porous carbon-supported FeCoNi bifunctional catalyst, synthesized via a spray combustion method.
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