Photocatalytic nitrogen fixation has attracted extensive attention in recent years. Studies have shown that catalytic materials with O, N and other defects can effectively reduce the bond energy of N[triple bond, length as m-dash]N triple bond when N is adsorbed on the defects. As an outstanding non-metallic catalyst, g-CN has been widely studied in the field of photocatalytic catalysis, and the nitrogen-defected CN shows promoted photocatalytic activity. Herein, nano-size MOF-74 particles (<20 nm) was dispersed on nitrogen-defected CN thin film (∼4 nm) a simple sol-gel method. The combination of Nano-MOF and defected film CN could effectively improve the photocatalytic activity of nitrogen fixation through Z-scheme mechanism compared with pure defected film CN.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055406 | PMC |
| http://dx.doi.org/10.1039/d0ra03562a | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Nitrogen Modified Linear Polythiophene Derivatives with Polarized Charge Distribution for Red Light-Induced Photocatalysis.
ChemSusChem
January 2025
Fuzhou University, College of Chemistry, Xueyuan Road 2, 350108, Fuzhou, CHINA.
Elevating the long-wavelength activation of photocatalysts represents a formidable approach to optimizing sunlight utilization. Polythiophene (PTh), although renowned for its robust light absorption and excellent conductivity, is largely overlooked for its potential as a photocatalyst due to the swift recombination of photogenerated charge carriers. Herein, we unveil that the strategic introduction of an aromatic ring containing varying nitrogen content into PTh instigates polarized charge distribution and facilitates the narrowing of the band gap, thereby achieving efficient photocatalytic activities for both hydrogen and hydrogen peroxide generation.
View Article and Find Full Text PDFPhotocatalytic upcycling of polylactic acid to alanine by sulfur vacancy-rich cadmium sulfide.
Nat Commun
January 2025
Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117585, Singapore, Singapore.
Photocatalytic conversion has emerged as a promising strategy for harnessing renewable solar energy in the valorization of plastic waste. However, research on the photocatalytic transformation of plastics into valuable nitrogen-containing chemicals remains limited. In this study, we present a visible-light-driven pathway for the conversion of polylactic acid (PLA) into alanine under mild conditions.
View Article and Find Full Text PDFEngineering Planar Crystallinity in Nitrogen-Vacancy-Incorporated Carbon Nitride for Efficient Photoredox Catalysis.
ACS Appl Mater Interfaces
January 2025
Key Laboratory of Functional Inorganic Material Chemistry, Ministry of Education of the People's Republic of China, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.
The concurrent evolution of value-added benzimidazole compounds and hydrogen within the domain of chemical synthesis is of paramount importance. The utilization of photocatalysis enhances both the efficiency and environmental benignity of the synthetic process. However, it is profoundly challenging within a photocatalytic system to simultaneously augment the number of active sites and the internal transport rate of photogenerated charge carriers.
View Article and Find Full Text PDFEngineering Defect-Mediated S-scheme heterojunctions in MOF-Derived N-doped NiO porous microrods and ZnInS nanosheets for superior photocatalytic hydrogen evolution.
J Colloid Interface Sci
January 2025
Institute of Micro/Nano Materials and Devices, Ningbo University of Technology, Ningbo 315211 PR China. Electronic address:
The development of efficient photocatalysts inspired by natural photosynthesis has drawn considerable interest for sustainable hydrogen (H) production. Among the various strategies for enhancing H evolution, constructing step-scheme (S-scheme) heterojunctions has attracted extensive interest, thanks to their limited charge recombination and enhanced charge transport in comparison to the traditional photocatalytic systems. Herein, we report the engineering of a novel S-scheme heterojunction by integrating ultrathin ZnInS (ZIS) nanosheets with MOF-derived N-doped NiO porous microrods (ZIS/N-NiO) toward superior photocatalytic behaviors.
View Article and Find Full Text PDFA Review of Laboratory Studies on the Heterogeneous Chemistry of NO: Mechanisms and Uptake Kinetics.
J Phys Chem A
January 2025
State Key Joint Laboratory of Environment Simulation and Pollution Control, Research Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China.
NO is a significant primary atmospheric pollutant that plays a key role in atmospheric chemistry. It serves as a crucial precursor to photochemical smog, acid rain, and secondary particulate matter and is instrumental in determining the atmospheric oxidation capacity. In this review, we focus on the heterogeneous chemistry of NO, which has been demonstrated to significantly influence the sources and sinks of various nitrogen-containing species through field measurements and model simulations.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!