DMSO was found to activate arylisothiocyanates for self-nucleophilic addition. A subsequent intramolecular C-H sulfurization catalyzed by PdBr enables access to a wide range of 2-aminobenzothiazole derivatives in moderate to good yields. This is the first example of a DMSO-mediated Pd-catalyzed synthesis of 2-aminobenzothiazoles through cyclization/C-H sulfurization of two isothiocyanates.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9060301 | PMC |
| http://dx.doi.org/10.1039/c8ra09784d | DOI Listing |
Publication Analysis
Top Keywords
Similar Publications
Ligand-Induced Intramolecular Cuprophilic and Argentophilic Interactions in Bimetallic Cu(I) and Ag(I) Phosphine Complexes and the Assessment of Their Antityrosinase and Antibacterial Effects.
Inorg Chem
January 2025
Department of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, 3012 Bern, Switzerland.
Binuclear silver(I) and copper(I) complexes, and , with bridging diphenylphosphine ligands were prepared. In , the silver(I) center is located inside a trigonal plane composed of three phosphorus donors from three separate and bridging dppm ligands. The fourth coordination site is filled with neighboring silver(I) ions.
View Article and Find Full Text PDFC-H Bond Activation by Sulfated Zirconium Oxide is Mediated by a Sulfur-Centered Lewis Superacid.
Angew Chem Int Ed Engl
December 2024
Department of chemistry, University of California, Riverside, Riverside, CA, 92521, USA.
Sulfated zirconium oxide (SZO) catalyzes the hydrogenolysis of isotactic polypropylene (iPP, M=13.3 kDa, Đ=2.4,
Transition metal-catalyzed cascade C-H activation/cyclization with alkynes: an update on sulfur-containing directing groups.
Chem Commun (Camb)
December 2024
Department of Material and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, P. R. China.
In light of the extensive applications of sulfur-containing heterocyclic compounds in drug discovery, agrochemicals, and advanced materials, the construction of complex sulfur-containing molecular scaffolds has flourished in recent years. There is a profound interest in synthetic methods for forming carbon-sulfur bonds. Regarding this, transition metal (TM)-catalyzed C-H bond activation has emerged as a valuable means for the rapid formation of C-S bonds, although it is comparatively less explored than C-N or C-C bonds.
View Article and Find Full Text PDFA sulfur-templated Ni-Ni' coordination polymer that relies on a polarizable nickel nitrosyl hub.
Dalton Trans
December 2024
Department of Chemistry, Texas A & M University, College Station, Texas 77843, USA.
The templating properties of a diaza-nickel--dithiolate towards triphenylphosphine gold(I), yielding a [Ni(NS)·2Au(PPh)] complex (T. A. Pinder, S.
View Article and Find Full Text PDFSynthesis of Arenesulfenyl Fluorides and Fluorosulfenylation of Alkenes, Alkynes, and α-Diazocarbonyl Compounds.
Angew Chem Int Ed Engl
December 2024
Department of Chemistry and Chemical Biology, Harvard University Cambridge, Massachusetts, 02138, United States.
Sulfenyl fluorides are organic compounds of sulfur in formal oxidation state +2 with the formula R-S-F. Although the chloride, bromide, and iodide analogues have been extensively described in the literature, arenesulfenyl fluorides remain essentially unstudied. These structures have been implicated as putative intermediates in established processes to access polyfluorinated sulfur species; however, definitive and direct evidence of their existence has not been obtained, nor has a systematic understanding of their reactivity.
View Article and Find Full Text PDFWant AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!