Based on MS analysis, the mechanism of the Baeyer-Villiger oxidation of cyclic ketones with hydrogen peroxide using metal triflates (Ga(OTf) and Er(OTf)) as catalysts was proposed. In the case of cyclohexanone as a substrate, dimeric, trimeric and tetrameric peroxide structures were detected.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9054370 | PMC |
| http://dx.doi.org/10.1039/d0ra03335a | DOI Listing |
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