Strategies for the synthesis of star-shaped molecules have been in high demand in the last decades due to the importance of those compounds in various fields. The distinctly different properties of these compounds compared to their linear analogues make them versatile building blocks for the formation of mesophases of interesting mesomorphic and photophysical properties. Moreover, the applications of star-shaped molecules as building units for dendrimers as well as in supramolecular host-guest chemistry have also been recently studied. The star-shaped molecules mentioned in this review are classified according to the central core as well as the type of side arms. The properties and applications of these compounds are described in the appropriate contexts. This report summarizes the recent advances in this area.
Download full-text PDF |
Source |
---|---|
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9064441 | PMC |
http://dx.doi.org/10.1039/c9ra02749a | DOI Listing |
Molecules
December 2024
Institute for Computation in Molecular and Materials Science, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.
Branched-structure polyarylacetylene resins with low curing temperatures and excellent thermal stability are promising candidates for high-performance resin-matrix composites. In this work, the effects of different vinyl/acetylene group ratios on the thermal properties of star-shaped silicon-containing arylacetylene (SSA) resins and branched silicon-containing arylacetylene (BSA) resins were investigated by molecular dynamics simulations. The calculated interaction energies, diffusion behaviors, and glass transition temperatures () indicated that an increase in the vinyl/acetylene group ratio positively affected the rheological and thermal properties of the branched resins.
View Article and Find Full Text PDFMolecules
November 2024
College of Traditional Chinese Medicine, Xinjiang Medical University, Urumqi 830017, China.
, a deciduous shrub from the Adoxaceae family, is a traditional Kazakh medicine used in Xinjiang, China. Its branches, leaves, and fruits are used to treat fractures, rheumatoid arthritis, and nephritis. To advance research on , we conducted studies on its microscopic identification, chemical composition, and biological activity.
View Article and Find Full Text PDFSmall
December 2024
Department of Gynaecology and Obstetrics, Shanghai Key Laboratory of Anesthesiology and Brain Functional Modulation, Clinical Research Center for Anesthesiology and Perioperative Medicine Translational Research Institute of Brain and Brain-Like Intelligence, Shanghai Fourth People's Hospital School of Medicine, Tongji University, Shanghai, 200434, China.
Antimicrobial and antioxidant packaging films play a crucial role in extending food shelf life, maintaining quality, and enhancing safety by inhibiting microbial growth and slowing oxidation processes. However, most commercial preservative films suffer from limited antimicrobial and antioxidant properties. Moreover, these films are made from petroleum-based materials that degrade into microplastics, resulting in environmental contamination and potential health risks for humans.
View Article and Find Full Text PDFLangmuir
December 2024
Université Paris-Saclay, CEA, CNRS, SPEC, TITANS, Gif sur Yvette F-91191, France.
The self-assembly of star-shaped 1,3,5-tris(4-carboxyphenyl)benzene molecules on Au(111) is investigated by using scanning tunneling microscopy (STM) and density functional theory (DFT) calculations. STM shows that for one monolayer deposition, the molecules self-assemble into two compact nanoarchitectures: one with a rectangular unit cell and a second one with a parallelogram unit cell. DFT calculations reveal that these two compact structures are stabilized by hydrogen bonds and that the rectangular nanoarchitecture has the lowest energy.
View Article and Find Full Text PDFNan Fang Yi Ke Da Xue Xue Bao
October 2024
Xiyuan Hospital, China Academy of Chinese Medical Sciences, Beijing 100091, China.
Objective: To culture and expand primary rat aortic vascular stem cells in vitro and evaluate their characteristics as mesenchymal stem cells.
Methods: The thoracic and abdominal aortas isolated from 2- to 3-week-old Sprague-Dawley rats were cut into vascular segments 2.0 mm in length and cultured in culture flasks till adhesion and solidification of the outer membranes.
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!