4,4-Difluoro-4-bora-3,4-diaza--indacenes (F-BODIPYs) are deprotected through removal of the -BF moiety upon treatment with methylboronic acid. The tolerance of various substitution patterns about the dipyrrinato core is demonstrated the deprotection of thirteen F-BODIPYs and an F-aza-BODIPY. Work-up with aq. HBr affords the desired dipyrin HBr salt in quantitative yield without need for purification.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055154 | PMC |
| http://dx.doi.org/10.1039/d0ra05151a | DOI Listing |
Publication Analysis
Top Keywords
methylboronic acid
8
facile deprotection
4
deprotection f-bodipys
4
f-bodipys methylboronic
4
acid 44-difluoro-4-bora-34-diaza--indacenes
4
44-difluoro-4-bora-34-diaza--indacenes f-bodipys
4
f-bodipys deprotected
4
deprotected removal
4
removal -bf
4
-bf moiety
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!