AI Article Synopsis

  • The CoFeMnTiVZr alloy, created through rapid solidification, has a hexagonal Laves-phase structure and is analyzed for its electrochemical properties in hydrogen absorption/desorption.
  • Cyclic voltammetry and electrochemical impedance spectroscopy reveal important details about the kinetics and efficiency of hydrogen storage within the alloy under varying voltage conditions.
  • The alloy showcases a maximum hydrogen capacity of about 1.9 wt% at room temperature, with a consistent capacity of 1.7 wt% noted in gas-solid reactions, demonstrating its reliability for reversible hydrogen absorption.

Article Abstract

The single-phase multi-principal-component CoFeMnTiVZr alloy was obtained by rapid solidification and examined by a combination of electrochemical methods and gas-solid reactions. X-ray diffraction and high-resolution transmission electron microscopy analyses reveal a hexagonal Laves-phase structure (type C14). Cyclic voltammetry and electrochemical impedance spectroscopy investigations in the hydrogen absorption/desorption region give insight into the absorption/desorption kinetics and the change in the desorption charge in terms of the applied potential. The thickness of the hydrogen absorption layer obtained by the electrochemical reaction is estimated by high-resolution transmission electron microscopy. The electrochemical hydrogen storage capacity for a given applied voltage is calculated from a series of chronoamperometry and cyclic voltammetry measurements. The selected alloy exhibits good stability for reversible hydrogen absorption and demonstrates a maximum hydrogen capacity of ∼1.9 wt% at room temperature. The amount of hydrogen absorbed in the gas-solid reaction reaches 1.7 wt% at 298 K and 5 MPa, evidencing a good correlation with the electrochemical results.

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Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9055208PMC
http://dx.doi.org/10.1039/d0ra04089dDOI Listing

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