Effective edge oxidation of graphene with high structural integrity is highly desirable yet technically challenging for most practical applications. In this work, we have developed a green and facile strategy to obtain edge-oxidized graphene with good dispersion stability and high electrical conductivity by exploiting high edge reactivity of highly conductive multi-layer graphene and oxidizing radicals (SO ˙) generated from sodium persulfate (NaSO) with ferrous ion (Fe) activation. Owing to high structural integrity of pristine graphene and effective edge oxidation, the obtained edge-oxidized graphene exhibited excellent dispersion stability and satisfactory electrical conductivity ( ≥240 S cm). Moreover, the oxidation degree of pristine graphene can be well controlled by adjusting treatment time. The obtained edge-oxidized graphene is expected to find a variety of applications in many fields of anti-static films, energy storage materials, flexible sensors and high-performance nanocomposites.
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http://dx.doi.org/10.1039/d0ra05575a | DOI Listing |
Materials (Basel)
December 2024
Department of Civil Engineering, College of Engineering, Kyung Hee University, Yongin 17104, Republic of Korea.
Edge-oxidized graphene oxide (EOGO) is a nano-sized material that is chemically stable and easily mixed with water due to its hydrophilic properties; thus, it has been used in various engineering fields, particularly for the reinforcement of building and construction materials. In this study, the effect of EOGO in soil reinforcement was investigated. When mixed with soil, it affects the mechanical properties of the soil-GO mixture.
View Article and Find Full Text PDFACS Appl Mater Interfaces
September 2024
Nano Materials Research Division, Korea Institute of Materials Science (KIMS), 797 Changwon-daero, Seongsan-gu, Changwon-si, Gyeongsangnam-do 51508, Republic of Korea.
Using three-dimensional (3D) printing technology to fabricate BiTe-based thermoelectric (TE) generators opens a potential way to create shape-conformable devices capable of recovering waste heat from thermal energy sources with diverse surface morphologies. However, pores formed in 3D-printed BiTe-based materials by the removal of the organic ink binder result in unsatisfactory performance compared to the bulk materials, which has limited the widespread application of the ink-based 3D printing process. Furthermore, managing the volatile Se element in the n-type materials poses significant technological challenges compared to the p-type counterparts, resulting in a scarcity of research on 3D printing of n-type BiTe.
View Article and Find Full Text PDFPolymers (Basel)
July 2024
Department of Civil Engineering, College of Engineering, King Saud University, P.O. Box 800, Riyadh 11421, Saudi Arabia.
Scrap tires have become one of the most serious environmental issues worldwide in recent years. Exploiting this scrap has caught the attention of researchers in their efforts to conserve the environment. From a structural engineering materials perspective, a partial fine aggregate in cement mortar can be replaced by crumb rubber produced from scrap tires.
View Article and Find Full Text PDFInt J Mol Sci
June 2023
Department of Electrical and Computer Engineering, College of Electrical and Computer Engineering, National Yang Ming Chiao Tung University, Hsinchu 300, Taiwan.
Graphene oxide-based materials (GOBMs) have been widely explored as nano-reinforcements in cementitious composites due to their unique properties. Oxygen-containing functional groups in GOBMs are crucial for enhancing the microstructure of cementitious composites. A better comprehension of their surface chemistry and mechanisms is required to advance the potential applications in cementitious composites of functionalized GOBMs.
View Article and Find Full Text PDFNanoscale
July 2023
Department of Chemistry, SRM University-AP, Andhra Pradesh, Neerukonda, Guntur (Dt), Andhra Pradesh, 522240, India.
Clean water and sanitation are two of the most important challenges worldwide and the main source for freshwater is groundwater. Nowadays, water is polluted by human activities. Concern about the presence of nitrates (NO) in groundwater is increasing day-by-day due to the intensive use of fertilizers and other anthropogenic sources, such as sewage or industrial wastewater discharge.
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