Various borohydrides were found to catalyze the redistribution reaction of hydrosilane and chlorosilane in different solvents to produce hydrochlorosilanes efficiently and facilely. The redistribution reaction was affected by solvent and catalyst. The substrate scope was investigated in HMPA with LiBH as catalyst. A possible mechanism was proposed to explain the redistribution process.
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|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9053603 | PMC |
| http://dx.doi.org/10.1039/d0ra03536j | DOI Listing |
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