Adsorption has been the focus of research on the treatment of heavy metal mercury pollution since it is among the most toxic heavy metals in existence. The US EPA has set a mandatory discharge limit of 10 μg Hg L for wastewater and for drinking water a maximum accepted concentration of 1 μg Hg L. Physical adsorption and chemical adsorption are the two major mechanisms of adsorption methods used for mercury removal in aqueous sources. The recent decades' research progress is reviewed to elaborate varieties of adsorption materials ranging from materials with large surface area for physical adsorption to metal oxides for chemical adsorption. Many examples are presented to illustrate the adsorption principles and clarify the relationship between the structure and performance of the adsorbents. The combination of physical adsorption and chemical adsorption gives rise to numbers of potential mercury removal composites. This review demonstrates the adsorption mechanism and the performance of varieties of adsorbents, which would provide a comprehensive understanding on the design and fabrication of new materials for the removal of heavy metal ions in water.

Download full-text PDF

Source
http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066024PMC
http://dx.doi.org/10.1039/c9ra01924cDOI Listing

Publication Analysis

Top Keywords

chemical adsorption
16
adsorption
12
physical adsorption
12
adsorption principles
8
heavy metal
8
adsorption chemical
8
mercury removal
8
removal
4
removal hgii
4
hgii aqueous
4

Similar Publications

Designing efficient Ruthenium-based catalysts as practical anodes is of critical importance in proton exchange membrane water electrolysis. Here, we develop a self-assembly technique to synthesize 1 nm-thick rutile-structured high-entropy oxides (RuIrFeCoCrO) from naked metal ions assembly and oxidation at air-molten salt interface. The RuIrFeCoCrO requires an overpotential of 185 mV at 10 m A cm and maintains the high activity for over 1000 h in an acidic electrolyte via the adsorption evolution mechanism.

View Article and Find Full Text PDF

A chitosan-based sensing membrane for on-site and sensitive dual-channel portable detection and efficient adsorption of Pb in groundwater.

Anal Chim Acta

February 2025

State Key Laboratory of Applied Organic Chemistry and Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province, College of Chemistry and Chemical Engineering, Lanzhou University, Gansu, Lanzhou, 730000, China. Electronic address:

The presence of lead ion (Pb) in groundwater poses a serious risk to human health, even at low levels. Therefore, it is essential to develop a new strategy for both selective detection and effective removal of Pb in groundwater, which has been rarely reported. Here, we developed a multi-functional chitosan-based fluorescent sensing membrane (CM-L/CG) by using a casting method for the sensitive/selective detection and removal of Pb in groundwater.

View Article and Find Full Text PDF

Nanocellulose/activated carbon composite aerogel beads with high adsorption capacity for toxins in blood.

Int J Biol Macromol

January 2025

School of Chemistry, Chemical Engineering and Life Sciences, Wuhan University of Technology, Luoshi Road 122, Wuhan 430070, China; School of Materials Science and Engineering, Wuhan University of Technology, Luoshi Road 122, Wuhan 430070, China. Electronic address:

Activated carbon is extensively utilized in blood purification applications. However, its performance has been significantly limited by their poor blood compatibility. In this work, 2,2,6,6-tetramethylpiperidinyl-1-oxyl (TEMPO)-oxidized cellulose nanofibers (TOCN) and activated carbon (AC) were used to form composite beads by the drop curing method to improve hemocompatibility.

View Article and Find Full Text PDF

Cellulose/covalent organic framework aerogel for efficient removal of Cr(VI): Performance and mechanism study.

Int J Biol Macromol

January 2025

Yunnan Provincial Key Laboratory of Wood Adhesives and Glued Products, Southwest Forestry University, Kunming 650224, Yunnan, China. Electronic address:

Cellulose composites have exceptional qualities, particularly in removing heavy metal ions. Nevertheless, these materials' poor mechanical qualities and the restricted exposure of surface-active sites reduce the effectiveness of their removal. The removal efficiency of adsorbent materials largely depends on their macroscopic structural characteristics.

View Article and Find Full Text PDF

For the effective removal of phenol from the environment, photocatalytic synergistic adsorption is currently one of the key methods. By leveraging the polysaccharide backbone structure of sodium alginate (SA),Zinc hydroxystannate (ZHS) was introduced into the gel structure using a co-precipitation technique. Additionally, gangue waste was repurposed through a polymerization reaction.

View Article and Find Full Text PDF

Want AI Summaries of new PubMed Abstracts delivered to your In-box?

Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!