The empirical solubility of hydrocarbon fluids, polyalphaolefin (PAO) and mineral oil, in thirteen small molecular weight alcohols (C-C) was determined. Butanols, pentanols, and 1-hexanol could dissolve up to PAO-10 and mineral oil. -Pentanol and 1-hexanol could also dissolve high-viscosity PAO-150. The dialkyl carbonate of fusel oil (DFC) was synthesized from dimethyl carbonate in 69% yield. DFC had excellent non-polar solubility and could dissolve PAO-150 and several common industrial lubricants. The flash point of DFC was 93 °C, more than twice that of isoamyl alcohol. DFC had net heating value of 30.47 MJ kg, nearly double that of dimethyl carbonate. However, its derived cetane number of 22.8 indicates DFC could not be used directly as diesel fuel.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9067106 | PMC |
| http://dx.doi.org/10.1039/c9ra04220b | DOI Listing |
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