The accurate prediction of the basicity of tertiary phosphines in acetonitrile and water is reported by the linear correlation between computed Δp's obtained by density functional theory (DFT) and experimental values extracted from the literature. This method is applied to the prediction of p values of 9-phosphatriptycene derivatives and showed that they are weaker Brønsted bases than their triphenylphosphine analogues. This lower reactivity is attributed to their high pyramidalization that increases their lone pair 3s character, stabilizing its energy level. Their potential application in frustrated Lewis pair chemistry is then considered by investigating the hydrogenation of 1,1-diphenylethylene by the tris(pentafluorophenyl)borane/1-chloro-9-phosphatriptycene frustrated Lewis pair.
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