Polyhedral metallocalixarene nanocage clusters based on pure Ti(IV) ions are to our knowledge unknown hitherto. Herein we report the first Ti(IV)-based metallocalixarene nanocage cluster by assembling a [TiO] cage with six -butylcalix[4]arene molecules. Notably, the cluster exhibits extraordinary stability in high-concentration acid/alkali solutions and can act as a stable photocatalyst to catalyze the oxidation of ammonia to imines.
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| http://dx.doi.org/10.1039/d2cc01740g | DOI Listing |
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