The edge chlorination of the benchmark nanographenes triphenylene and hexa--hexabenzocoronene is conducted mechanochemically. This approach overcomes solubility limitations and eliminates the need for elaborate chlorination conditions. Additionally, the planarization of oligophenylenes and their edge-chlorination can be combined in a one-pot approach requiring as little as 60 minutes.
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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9044044 | PMC |
http://dx.doi.org/10.1039/d1ra07679e | DOI Listing |
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