This study investigated the effect of a modified 13X zeolite to Pd/zeolite catalyst on the oxidation of hydrogen to ensure safety from hydrogen leakage. The catalytic activity of Pd/zeolite catalysts was significantly affected by acid treatment of 13X zeolite support and various calcination temperatures (300 °C, 400 °C, 500 °C, 600 °C) of the Pd/zeolite catalyst. To understand the correlation between the activity and physical properties of the catalysts, activity test, XRD, BET, TEM, TPR, and TPO were performed; Pd/13X (400) was shown to have a high catalytic activity, which depended on the dispersion and particle size of palladium. Also, a strong PdH on the catalyst surface was formed, and a high catalytic activity at a low hydrogen concentration was obtained.
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| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9043908 | PMC |
| http://dx.doi.org/10.1039/d1ra06395b | DOI Listing |
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