The reaction order and Arrhenius activation parameters for spontaneous hydrogen release from cyclic amine boranes, , BN-cycloalkanes, were determined for 1,2-BN-cyclohexane (1) and 3-methyl-1,2-BN-cyclopentane (2) in tetraglyme. Computational analysis identified a mechanism involving catalytic substrate activation by a ring-opened form of 1 or 2 as being consistent with experimental observations.
Download full-text PDF |
Source |
|---|---|
| http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9042405 | PMC |
| http://dx.doi.org/10.1039/d1ra07477f | DOI Listing |
Publication Analysis
Top Keywords
hydrogen release
8
comparison hydrogen
4
release kinetics
4
kinetics 6-membered
4
6-membered 12-bn-cycloalkanes
4
12-bn-cycloalkanes reaction
4
reaction order
4
order arrhenius
4
arrhenius activation
4
activation parameters
4
Similar Publications
Want AI Summaries of new PubMed Abstracts delivered to your In-box?
Enter search terms and have AI summaries delivered each week - change queries or unsubscribe any time!