Fluoride-ion induced hydrolysis of imine (C[double bond, length as m-dash]N) bonds has not been documented in the literature, in spite of the numerous salicylidene-based fluoride sensors studied over the years. Herein, we have proposed a mechanism for fluoride-ion induced hydrolysis of salicylidene compounds (SL and CL1-3) based on H-NMR, F-NMR, LC-MS and UV-vis spectroscopy experiments.

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http://www.ncbi.nlm.nih.gov/pmc/articles/PMC9052090PMC
http://dx.doi.org/10.1039/d0ra02293dDOI Listing

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