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A facile Fe(III)-catalyzed oxidative decarboxylative radical coupling reaction of α,α-difluoroarylacetic acids with coumarins has been developed. This transformation, which provides a series of C-3 difluoroarylmethylated coumarins containing various functional groups in moderate-to-good yields, features easily accessible starting materials and operational simplicity.

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An efficient and green strategy for the preparation of C3-difluoroarylmethylated quinoxalin-2(1)-one a visible-light-induced decarboxylative C3-difluoroarylmethylation of quinoxalin-2(1)-one with potassium 2,2-difluoro-2-arylacetate in water at room temperature was developed. This photoinduced reaction generated the desired products in good yields under simple and mild conditions.

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